Pesticidal mixtures

ABSTRACT

The present invention relates to pesticidal mixtures comprising one fungicidal compound I selected from the group consisting of 1-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one (I-1), 1-[3-bromo-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyllphenyl]-4- methyl-tetrazol-5-one (I-2), 1-[2-[[-1(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one (I-3), 1-[2-[[1(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro-phenyl]-4- methyl-tetrazol-5-one (I-4), 1-[2-[[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro- phenyl]-4-methyl-tetrazol-5-one (I-5), 1-[2-[[4-(4-chlorophenyl)thiazol-2-yl]oxymethyl]3-methyl-phenyl]-4-methyl-tetrazol-5-one (I-6), 1-[3-chloro-2-[[4-(p-tolyl)thiazol-2-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one (I-7), 1-[3- cyclopropyl-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one (I-8), 1-[3-(difluoromethoxy)-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one (I-9), 1-methyl-4-[3-methyl-2-[[2-methyl-4-(1- methylpyrazol-3-yl)phenoxy]methyl]phenyl]tetrazol-5-one (I-10) and 1-methyl-4-[3-methyl-2-[[1-[3-(trifluoromethyl)phenyl]ethylidene-aminoloxymethyl]phenyl]tetrazol-5-one (I-11) and) and 1-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one (I-12) and one or more fungicides.

This application is a continuation of U.S. application Ser. No.15/524,064, which is a U.S. National Stage application of InternationalApplication No. PCT/EP2015/074922, filed Oct. 28, 2015; this applicationalso claims priority under 35 U.S.C. § 119 to European PatentApplication No.

14192252.6, filed Nov. 7, 2014, and European Patent Application No.14198463.3, filed Dec. 17, 2014; all of the aforementioned applicationsare hereby incorporated herein by reference in their entirety.

DESCRIPTION

The present invention relates to fungicidal mixtures comprising

1) one fungicidal compound I selected from the group consisting of1-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one(I-1),1-[3-bromo-2-[[1-(4-chlorophenyl)pyrazol-3-yl]]phenyl1-4-methyl-tetrazol-5-one(I-2),1-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl1-3-methyl-phenyl]-4-methyl-tetrazol-5-one(I-3),1-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro-phenyl]-4-methyl-tetrazol-5-one(1-4),1-[2-[[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro-phenyl]-4-methyl-tetrazol-5he-one(I-5),1-[2-[[4-(4-chlorophenyl)thiazol-2-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one(1-6),1-[3-chloro-2-[[4-(p-tolypthiazol-2-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one(I-7),1-[3-cyclopropyl-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one(1-8),1-[3-(difluoromethoxy)-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one(I-9),1-methyl-4-[3-methyl-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]tetrazol-5-one(I-10) and1-methyl-4-[3-methyl-2-[[1-[3-(trifluoromethyl)phenyl]ethylideneaminoloxymethyl]phenyl]tetrazol-5-one(I-11) and1-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one(I-12); and

2) and at least one further fungicidal compound II selected from thegroup of strobilurines consisting of azoxystrobin (II-1), dimoxystrobin(II-2), fluoxastro-bin (II-3), kresoxim-methyl (II-4), mandestrobin(II-5), metaminostrobin (II-6), orysastrobin, (II-7), picoxystrobin(II-8), pyraclostrobin (II-9), trifloxystrobin (II-10), pyribencarb(II-11), famoxadone (II-12), fenamidone (II-13); and

the group of carboxamides selected from benzovindiflupyr (II-14),bixafen (II-15), boscalid (II-16), fluopyram (II-17), flutolanil(II-18), fluxapyroxad (II-19), isofetamid (II-20), isopyrazam (II-21),penflufen (II-22), penthiopyrad (II-23), sedaxane (II-24), 3(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl¬indan-4-yl)pyrazole-4-carboxamide(II-25), 3(trifluoromethyl)-1-methyl-N-(1,1,3-trimethyl¬indan-4-yl)pyrazole-4-carboxamide(II-26),1,3-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyr¬azole-4-carboxamide(II-27),3-(trifluorometh-yl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-carboxamide(II-28),1,3,5-tri-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4-car¬(II-29);and

the group of sterol biosynthesis inhibitors (SBI fungicides) consistingof bitertanol (II-30), bromuconazole (II-31), cyproconazole (II-32),difenoconazole (II-33), diniconazole (II-34), diniconazole-M (II-35),epoxiconazole (II-36), fenbuconazole (II-37), fluquinconazole (II-38),flusilazole (II-39), flutriafol (II-40), hexaconazole (II-41),imibenconazole (II-42), ipconazole (II-43), metconazole (II-44),myclobutanil (II-45), oxpoconazole (II-46), paclobutrazole (II-47),penconazole (II-48), propiconazole (II-49), prothioconazole (II-50),simeconazole (II-51), tebuconazole (II-52), tetraconazole (II-53),triadimefon (II-54), triadimenol (II-55), triticonazole (II-56),uniconazole (II-57),2-[rel-(2S;3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)-oxi-ranyl-methyl]-2H-[1,2,4]triazole-3-thiol(II-58); and

the group of sterol biosynthesis inhibitors (SBI fungicides) anddeltal4-reductase inhibitors consisting of dodemorph (II-59),dodemorph-acetate (II-60), fenpropimorph (II-61), tridemorph (II-62),fenpropidin (II-63), spiroxamine (II-64); and the group of inhibitors ofcell division and cytoskeleton consisting of benomyl (II-65),carbendazim (II-66), fuberidazole (II-67), thiabendazole (II-68),thiophanate-methyl (II-69); di-ethofencarb (II-70), ethaboxam (II-71),pencycuron (II-72), fluopicolide (II-73), zoxamide (II-74), metrafenone(II-75), pyriofenone (II-76); and

the group of inhibitors with Multi Site Action consisting of Bordeauxmixture, (II-77), copper acetate, (II-78), copper hydroxide, (II-79),copper oxychloride, (II-80), basic copper sulfate, (II-81), sulfur;(II-82), mancozeb, (II-83), maneb, (II-13), metam, (II-85), metiram,(II-86), propineb, (II-87), thiram, (II-88), zineb, (II-89), ziram;(II-90), chlorothalonil, (II-91), captan, (II-92), folpet, (II-93),phthalide, (II-94), dodine, (II-95), iminoctadine, (II-96), dithianon,(II-97),2,6-di-methyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetraone(II-98); and the group of cell wall synthesis inhibitors consisting ofvalidamycin (II-99), polyoxin B (II-100), pyroquilon (II-101),tricyclazole (II-102), carpropamid (II-103); and

the group of plant defence inducers consisting of acibenzolar-S-methyl(II-104), probenazole (II-105), isotianil (II-106), tiadinil (II-107),prohexadione-calcium (II-108), fosetyl (II-109), phosphorous acid andits salts (II-110); and

the group of respiration inhibitors consisting of cyazofamid (II-111),amisulbrom (II-112), dinocap (II-113), fluazinam (II-114), ferimzone(II-115), fentin salts, such as fentin-acetate, fentin chloride orfentin hydroxide, (II-116), ametoctradin (II-117), silthiofam (II-118);and the group of sterol biosynthesis inhibitors (SBI fungicides)consisting of imazalil (II-119), pefurazoate (II-120), prochloraz(II-121), triflumizol (II-122); and

the group of sterol biosynthesis inhibitors (SBI fungicides) consistingof fenarimol (II-123), pyrifenox (II-124), triforine (II-125),[3-(4-chloro-2-fluoro-phenyI)-5-(2,4-difluoro-phenyl)isoxazol-4-yl]-(3-pyridyl)methanol(II-126); and

the group of inhibitors of amino acid and protein synthesis consistingof cyprodinil (II-127), mepanipyrim (II-128), pyrimethanil (II-129),kasugamycin (II-130), streptomycin (II-131), polyoxin (II-132),validamycin A (II-133); and

the group of signal transduction inhibitors consisting of iprodione(II-134), procymidone (II-135), vinclozolin (II-136), fludioxonil(II-137), quinoxyfen (II-138); and the group of lipid and membranesynthesis inhibitors consisting of edifenphos (II-139), iprobenfos(II-140), isoprothiolane (II-141), tolclofos-methyl (II-142),dimethomorph (II-143), flumorph (II-144), mandipropamid (II-145),pyrimorph (II-146), benthiavalicarb (II-147), iprovalicarb (II-148),valifenalat (II-149), propamocarb (II-150), oxathiapiprolin (II-151),2-{3-[2-(1-([3,5-bis(di-fluoromethyl-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenylmethanesulfonate (G.5.2),2-{3-[2-(1-([3,5-bis(difluoro-methyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenylmethanesulfonate; (II-152); and the group of sterol biosynthesisinhibitors (SBI fungicides): Inhibitors of 3-keto reductase consistingof fenhexamid (II-153); and

the group of nucleic acid synthesis inhibitors consisting of benalaxyl(II-154), benalaxyl-M (II-155), kiralaxyl (II-156), metalaxyl (II-157),metalaxyl-M (mefenoxam) (II-158), oxadixyl (II-159), hymexazole(II-160), oxolinic acid (II-161), bupirimate (II-162), 5-fluorocytosine(II-163), 5-fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine (II-164),5-fluoro-2-(4-fluorophenyl-methoxy)pyrimidin-4-amine (II-165); and

the group of fungicides with unknown mode of action consisting ofcyflufenamid (II-166), cymoxanil (II-167), diclomezine (II-168),difenzoquat (II-169), difenzoquat-methylsulfate (II-170), fenpyrazamine(II-171), flumetover (II-172), flusulfamide (II-173), flutianil(II-174), oxa-thiapiprolin (II-175), tolprocarb (II-176), oxine-copper(II-177), proquinazid (II-178), tebuflo-quin (II-179), tecloftalam(II-180), picarbutrazox (II-181),3-[5-(4-chloro-phenyl)-2,3-dimethyl-isoxazolidin-3-yl]-pyridine(pyrisoxazole) (II-182),2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl1-1,3-thiazol-2-yl)piperidin-1-yl]etha-none(II-183),2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1-yl-oxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl1-1,3-thi-azol-2-yl)piperidin-1-yl]ethanone(II-113),2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-chloro-6-(prop-2-yn-1-yl-oxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl1-1,3-thiazol-2-yl)piperidin-1-yl]ethanone(II-185),2-[2-[(7,8-difluoro-2-methyl-3-quinolyl)oxy]-6-fluoro-phenyl]propan-2-ol(II-186),2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]-phen-yl]propan-2-01(II-187), 9-fluoro-2,2-dimethyl-5-(3-quinolyl)-3H-1,4-benzoxazepine(II-188),3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroiso-quinolin-1-yl)-quinoline(II-189),3-(4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-quin-oline(II-190),3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline(II-191).

The above-referred mixtures are herein below also referred as “inventivemixtures”.

Moreover, the invention relates to a method for controlling pests, thisrefers to includes animal pests and harmful fungi, using the inventivemixtures and to the use of compound I and compound II and optionally asecond compound II for preparing such mixtures, and also to compositionscomprising such mixtures.

Moreover, the invention relates to a method for controlling harmfulfungi, using the inventive mixtures of compound 1,11 and optionallysecond compound II and to the use of compound I and one or two compoundsII as defined above for preparing such mixtures, and also tocomposi-tions comprising such mixtures.

Additionally, the present invention also comprises a method forprotection of plant propagation material (preferably seed) from harmfulpests, such as fungi or insects, arachnids or nematodes comprisingcontacting the plant propagation materials (preferably seeds) with aninventive mixture in pesticidally effective amounts

The term “plant propagation material” is to be understood to denote allthe generative parts of the plant such as seeds and vegetative plantmaterial such as cuttings and tubers (e. g. potatoes), which can be usedfor the multiplication of the plant. This includes seeds, roots, fruits,tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants,including seedlings and young plants, which are to be transplanted aftergermination or after emergence from soil. These young plants may also beprotected before transplantation by a total or partial treatment byimmersion or pouring. In a particular preferred embodiment, the termpropagation material denotes seeds.

Additionally, the present invention also comprises a method forprotection of plant propagation material (preferably seed) from harmfulfungi comprising contacting the plant propagation materials (preferablyseeds) with the inventive mixture in pesticidally effective amounts.

Moreover, the invention relates to a method for controlling harmfulfungi using the inventive mixtures mixtures and to the use of thecompounds present in the inventive mixtures for preparing such mixtures,and also to compositions comprising such mixtures.

The present invention further relates to plant-protecting activeingredient mixtures having synergistically enhanced action of improvingthe health of plants and to a method of applying such inventive mixturesto the plants.

Compounds I as well as their pesticidal action and methods for producingthem are known e.g. from WO 2013/162072, WO 2013/162072, WO 2013/162072,WO 2013/162072, WO 2013/162072, WO 2013/162077, WO 2013/162077, WO2014/051161, WO 2014/051161, WO 2014/051165 and WO 2014/013223.Compounds II as well as their pesticidal action and methods forproducing them are generally known. For instance, they may be found inthe e-Pesticide Manual V5.2 (ISBN 978 1 901396 85 0) (2008-2011) amongother publications.

One typical problem arising in the field of pest control lies in theneed to reduce the dosage rates of the active ingredient in order toreduce or avoid unfavorable environmental or toxicological effectswhilst still allowing effective pest control.

In regard to the instant invention the term pests embrace harmful fungi.

Another problem encountered concerns the need to have available pestcontrol agents which are effective against a broad spectrum of harmfulfungi.

There also exists the need for pest control agents that combineknock-down activity with prolonged control, that is, fast action withlong lasting action.

Another difficulty in relation to the use of pesticides is that therepeated and exclusive application of an individual pesticidal compoundleads in many cases to a rapid selection of pests, that means animalpests, and harmful fungi, which have developed natural or adaptedresistance against the active compound in question. Therefore there is aneed for pest control agents that help prevent or overcome resistance.

Another problem underlying the present invention is the desire forcompositions that improve plants, a process which is commonly andhereinafter referred to as “plant health”.

The term plant health comprises various sorts of improvements of plantsthat are not connected to the control of pests. For example,advantageous properties that may be mentioned are improved cropcharacteristics including: emergence, crop yields, protein content, oilcontent, starch content, more developed root system (improved rootgrowth), improved stress tolerance (e.g. against drought, heat, salt,UV, water, cold), reduced ethylene (reduced production and/or inhibitionof reception), tillering increase, increase in plant height, bigger leafblade, less dead basal leaves, stronger tillers, greener leaf color,pigment content, photosynthetic activity, less input needed (such asfertilizers or water), less seeds needed, more productive tillers,earlier flowering, early grain maturity, less plant verse (lodging),increased shoot growth, enhanced plant vigor, increased plant stand andearly and better germination; or any other advantages familiar to aperson skilled in the art.

It was therefore an object of the present invention to providepesticidal mixtures which solve the problems of reducing the dosage rateand/or enhancing the spectrum of activity and/or combining knock-downactivity with prolonged control and/or to resistance management and/orpromoting the health of plants.

We have found that this object is in part or in whole achieved by themixtures comprising the active compounds defined in the outset.

Especially, it has been found that the mixtures as defined in the outsetshow markedly enhanced action against pests compared to the controlrates that are possible with the individual compounds and/or is suitableAfor improving the health of plants when applied to plants, parts ofplants, seeds, or at their locus of growth.

It has been found that the action of the inventive mixtures goes farbeyond the fungicidal and/or plant health improving action of the activecompounds present in the mixture alone (synergistic action).

Moreover, we have found that simultaneous, that is joint or separate,application of the compound I and the compound II and optionally secondcompound II or successive application of the compound I and the compoundII and optionally second compound II allows enhanced control of pests,that harmful fungi, compared to the control rates that are possible withthe individual compounds (synergistic mixtures).

Moreover, we have found that simultaneous, that is joint or separate,application of the compound I and the compound II and optionally secondcompound II or successive application of the compound I and the compoundII and optionall optionally second compound II allows enhanced controlof harmful fungi, compared to the control rates that are possible withthe individual compounds (synergistic mixtures).

Moreover, we have found that simultaneous, that is joint or separate,application of the compound I and the compound II and optionally secondcompound II or successive application of the compound I and the compoundII and optionally second compound II provides enhanced plant healtheffects compared to the plant health effects that are possible with theindividual compounds.

The ratio by weight of compound I and compound II in binary mixtures isfrom 20000:1 to 1:20000, from 500:1 to 1:500, preferably from 100:1 to1:100 more preferably from 50:1 to 1:50, most preferably from 20:1 to1:20, including also ratios from 10:1 to 1:10, 1:5 to 5:1 , or 1:1.

The ratio by weight of compound I, II and second compound II in eachcombination of two ingredients in the mixture of three ingredients isfrom 20000:1 to 1:20000, from 500:1 to 1:500, preferably from 100:1 to1:100 more preferably from 50:1 to 1:50, most preferably from 20:1 to1:20, in-cluding also ratios from 10:1 to 1:10, 1:5 to 5:1 , or 1:1.

The following binary mixtures set forth herein are subject to theteaching of the present invention.

In the tables A, B, C, D, E, F, G, H and Z-set forth below, compounds offormula I are abbreviated as follows:

No chemical name I-11-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one I-21-[3-bromo-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one I-31-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one I-41-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro-phenyl]-4-methyl-tetrazol-5-one I-51-[2-[[1-(2,4-dichlorophenyl)pyrazol-3-yl]oxymethyl]-3-fluoro-phenyl]-4-methyl-tetrazol-5-one I-61-[2-[[4-(4-chlorophenyl)thiazol-2-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one I-71-[3-chloro-2-[[4-(p-tolyl)thiazol-2-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one I-81-[3-cyclopropyl-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one I-91-[3-(difluoromethoxy)-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]-4-methyl-tetrazol-5-one I-101-methyl-4-[3-methyl-2-[[2-methyl-4-(1-methylpyrazol-3-yl)phenoxy]methyl]phenyl]tetrazol-5-one I-111-methyl-4-[3-methyl-2-[[1-[3-(trifluoromethyl)phenyl]ethylidene-amino]oxymethyl]phenyl]tetrazol-5-one I-121-[3-chloro-2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]phenyl]-4-methyl-tetrazol-5-one

In the tables A, B, C, D, E, F, G and H set forth below compounds II areabbreviated by the number in brackets behind the individual pestidcideas displayed on pages 1 to 3 of the present invention.

“I” is compound I, “II” is compound II”

TABLE A1 No I II M.A.1.1 I-1 II-1.1 M.A.1.2 I-1 II-1.2 M.A.1.3 I-1II-1.3 M.A.1.4 I-1 II-1.4 M.A.1.5 I-1 II-1.5 M.A.1.6 I-1 II-1.6 M.A.1.7I-1 II-1.7 M.A.1.8 I-1 II-1.8 M.A.1.9 I-1 II-1.9 M.A.1.10 I-1 II-1.10M.A.1.11 I-1 II-1.11 M.A.1.12 I-1 II-1.12 M.A.1.13 I-1 II-1.13

Table A2

Table A2 is as Table A1, in which the compound 1-1 is replaced bycompound 1-2, and the mixtures are named from M.A.2.1 to M.A.2.13. Inthe context of the present invention, each of the rows of Table A2corresponds to one mixture.

Table A3

Table A3 is as Table A1, in which the compound 1-1 is replaced bycompound 1-3, and the mixtures are named from M.A.3.1 to M.A.3.13. Inthe context of the present invention, each of the rows of Table A3corresponds to one mixture.

Table A4

Table A4A is as Table A1, in which the compound 1-1 is replaced bycompound 1-4, and the mixtures are named from M.A.4.1 to M.A.4.13. Inthe context of the present invention, each of the rows of Table A4corresponds to one mixture.

Table A5

Table A5 is as Table A1, in which the compound 1-1 is replaced bycompound 1-5, and the mixtures are named from M.A.5.1 to M.A.5.13. Inthe context of the present invention, each of the rows of Table A5corresponds to one mixture.

Table A6

Table A6 is as Table A1, in which the compound 1-1 is replaced bycompound 1-6, and the mixtures are named from M.A.6.1 to M.A.6.13. Inthe context of the present invention, each of the rows of Table A6corresponds to one mixture.

Table A7

Table A7 is as Table A1, in which the compound 1-1 is replaced bycompound 1-7, and the mixtures are named from M.A.7.1 to M.A.7.13. Inthe context of the present invention, each of the rows of Table A7corresponds to one mixture.

Table A8

Table A8 is as Table A1, in which the compound 1-1 is replaced bycompound 1-8, and the mixtures are named from M.A.8.1 to M.A.8.13. Inthe context of the present invention, each of the rows of Table A8corresponds to one mixture.

Table A9

Table A9 is as Table A1, in which the compound 1-1 is replaced bycompound 1-9, and the mixtures are named from M.A.9.1 to M.A.9.13. Inthe context of the present invention, each of the rows of Table A9corresponds to one mixture.

Table A10

Table A10 is as Table A1, in which the compound 1-1 is replaced bycompound 1-10, and the mixtures are named from M.A.10.1 to M.A.10.13. Inthe context of the present invention, each of the rows of Table A10corresponds to one mixture.

Table A11

Table A11 is as Table A1, in which the compound 1-1 is replaced bycompound 1-11, and the mixtures are named from M.A.11.1 to M.A.11.13. Inthe context of the present invention, each of the rows of Table A11corresponds to one mixture.

Table A12

Table A12 is as Table A1, in which the compound 1-1 is replaced bycompound 1-12, and the mixtures are named from M.A.12.1 to M.A.12.13. Inthe context of the present invention, each of the rows of Table Al2corresponds to one mixture.

All tables A are preferred embodiments of the present invention. Withintable Al to table A12, the following mixtures are preferred: M.A.1.1,M.A.1.4, M.A.1.5, M.A.1.6, M.A.1.8, M.A.1.9, M.A.1.10, M.A.2.1, M.A.2.4,M.A.2.5, M.A.2.6, M.A.2.8, M.A.2.9, M.A.2.10, M.A.3.1, M.A.3.4, M.A.3.5,M.A.3.6, M.A.3.8, M.A.3.9, M.A.3.10, M.A.4.1, M.A.4.4, M.A.4.5, M.A.4.6,M.A.4.8, M.A.4.9, M.A.4.10, M.A.5.1, M.A.5.4, M.A.5.5, M.A.5.6, M.A.5.8,M.A.5.9, M.A.5.10, M.A.6.1, M.A.6.4, M.A.6.5, M.A.6.6, M.A.6.8, M.A.6.9,M.A.6.10, M.A.7.1, M.A.7.4, M.A.7.5, M.A.7.6, M.A.7.8, M.A.7.9,M.A.7.10, M.A.8.1, M.A.8.4, M.A.8.5, M.A.8.6, M.A.8.8, M.A.8.9,M.A.8.10, M.A.9.1, M.A.9.4, M.A.9.5, M.A.9.6, M.A.9.8, M.A.9.9,M.A.9.10, M.A.10.1, M.A.10.4, M.A.10.5, M.A.10.6, M.A.10.8, M.A.10.9,M.A.10.10, M.A.11.1, M.A.11.4, M.A.11.5, M.A.11.6, M.A.11.8, M.A.11.9,M.A.11.10, M.A.12.1, M.A.12.4, M.A.12.5, M.A.12.6, M.A.12.8, M.A.12.9and M.A.12.10.

Within table A, the following mixtures are more preferred: M.A.1.4,M.A.1.9, M.A.2.4, M.A.2.9, M.A.3.4, M.A.3.9, M.A.4.4, M.A.4.9, M.A.5.4,M.A.5.9, M.A.6.4, M.A.6.9, M.A.7.4, M.A.7.9, M.A.8.4, M.A.8.9, M.A.9.4,M.A.9.9, M.A.10.4, M.A.10.9, M.A.11.4, M.A.11.9, M.A.12.4 and M.A.12.9.

TABLE B1 No I II M.B.1.1 I-1 II-14 M.B.1.2 I-1 II-15 M.B.1.3 I-1 II-16M.B.1.4 I-1 II-17 M.B.1.5 I-1 II-18 M.B.1.6 I-1 II-19 M.B.1.7 I-1 II-20M.B.1.8 I-1 II-21 M.B.1.9 I-1 II-22 M.B.1.10 I-1 II-23 M.B.1.11 I-1II-24 M.B.1.12 I-1 II-25 M.B.1.13 I-1 II-26 M.B.1.14 I-1 II-27 M.B.1.15I-1 II-28 M.B.1.16 I-1 II-29

Table B2

Table B2 is as Table B1, in which the compound 1-1 is replaced bycompound 1-2, and the mixtures are named from M.B.2.1 to M.B.2.16. Inthe context of the present invention, each of the rows of Table B2corresponds to one mixture.

Table B3

Table B3 is as Table B1, in which the compound 1-1 is replaced bycompound 1-3, and the mixtures are named from M.B.3.1 to M.B.3.16. Inthe context of the present invention, each of the rows of Table B3corresponds to one mixture.

Table B4

Table B4A is as Table B1, in which the compound 1-1 is replaced bycompound 1-4, and the mixtures are named from M.B.4.1 to M.B.4.16. Inthe context of the present invention, each of the rows of Table B4corresponds to one mixture.

Table B5

Table B5 is as Table B1, in which the compound 1-1 is replaced bycompound 1-5, and the mixtures are named from M.B.5.1 to M.B.5.16. Inthe context of the present invention, each of the rows of Table B5corresponds to one mixture.

Table B6

Table B6 is as Table B1, in which the compound 1-1 is replaced bycompound 1-6, and the mixtures are named from M.B.6.1 to M.B.6.16. Inthe context of the present invention, each of the rows of Table B6corresponds to one mixture.

Table B7

Table B7 is as Table B1, in which the compound 1-1 is replaced bycompound 1-7, and the mixtures are named from M.B.7.1 to M.B.7.16. Inthe context of the present invention, each of the rows of Table B7corresponds to one mixture.

Table B8

Table B8 is as Table B1, in which the compound 1-1 is replaced bycompound 1-8, and the mixtures are named from M.B.8.1 to M.B.8.16. Inthe context of the present invention, each of the rows of Table B8corresponds to one mixture.

Table B9

Table B9 is as Table B1, in which the compound 1-1 is replaced bycompound 1-9, and the mixtures are named from M.B.9.1 to M.B.9.16. Inthe context of the present invention, each of the rows of Table B9corresponds to one mixture.

Table B10

Table B10 is as Table B1, in which the compound 1-1 is replaced bycompound 1-10, and the mixtures are named from M.B.10.1 to M.B.10.16. Inthe context of the present invention, each of the rows of Table B10corresponds to one mixture.

Table B11

Table B11 is as Table B1, in which the compound 1-1 is replaced bycompound 1-11, and the mixtures are named from M.B.11.1 to M.B.11.16. Inthe context of the present invention, each of the rows of Table B11corresponds to one mixture.

Table B12

Table B12 is as Table B1, in which the compound 1-1 is replaced bycompound 1-12, and the mixtures are named from M.B.12.1 to M.B.12.16. Inthe context of the present invention, each of the rows of Table B12corresponds to one mixture.

All tables B are preferred embodiments of the present invention. Withintable B1 to table B12, the following mixtures are preferred:

M.B.1.1, M.B.1.2, M.B.1.3, M.B.1.4, M.B.1.6, M.B.1.12, M.B.1.13,M.B.1.14, M.B.1.15, M.B.1.16, M.B.2.1, M.B.2.2, M.B.2.3, M.B.2.4,M.B.2.6, M.B.2.12, M.B.2.13, M.B.2.14, M.B.2.15, M.B.2.16, M.B.3.1,M.B.3.2, M.B.3.3, M.B.3.4, M.B.3.6, M.B.3.12, M.B.3.13, M.B.3.14,M.B.3.15, M.B.3.16, M.B.4.1, M.B.4.2, M.B.4.3, M.B.4.4, M.B.4.6,M.B.4.12, M.B.4.13, M.B.4.14, M.B.4.15, M.B.4.16, M.B.5.1, M.B.5.2,M.B.5.3, M.B.5.4, M.B.5.6, M.B.5.12, M.B.5.13, M.B.5.14, M.B.5.15,M.B.5.16, M.B.6.1, M.B.6.2, M.B.6.3, M.B.6.4, M.B.6.6, M.B.6.12,M.B.6.13, M.B.6.14, M.B.6.15, M.B.6.16, M.B.7.1, M.B.7.2, M.B.7.3,M.B.7.4, M.B.7.6, M.B.7.12, M.B.7.13, M.B.7.14, M.B.7.15, M.B.7.16,M.B.8.1, M.B.8.2, M.B.8.3, M.B.8.4, M.B.8.6, M.B.8.12, M.B.8.13,M.B.8.14, M.B.8.15, M.B.8.16, M.B.9.1, M.B.9.2, M.B.9.3, M.B.9.4,M.B.9.6, M.B.9.12, M.B.9.13, M.B.9.14, M.B.9.15, M.B.9.16, M.B.10.1,M.B.10.2, M.B.10.3, M.B.10.4, M.B.10.6, M.B.10.12, M.B.10.13, M.B.10.14,M.B.10.15, M.B.10.16, M.B.11.1, M.B.11.2, M.B.11.3, M.B.11.4, M.B.11.6,M.B.11.12, M.B.11.13, M.B.11.14, M.B.11.15, M.B.11.16, M.B.12.1,M.B.12.2, M.B.12.3, M.B.12.4, M.B.12.6, M.B.12.12, M.B.12.13, M.B.12.14,M.B.12.15 and M.B.12.16.

Witin table B1 to table B12, the following mixtures aremore preferred:

M.B.1.3, M.B.1.6, M.B.2.3, M.B.2.6, M.B.3.3, M.B.3.6, M.B.4.3, M.B.4.6,M.B.5.3, M.B.5.6, M.B.6.3, M.B.6.6, M.B.7.3, M.B.7.6, M.B.8.3, M.B.8.6,M.B.9.3, M.B.9.6, M.B.10.3, M.B.10.6, M.B.11.3, M.B.11.6, M.B.12.3 andM.B.12.6.

TABLE C1 No I II M.C.1.1 I-1 II-30 M.C.1.2 I-1 II-31 M.C.1.3 I-1 II-32M.C.1.4 I-1 II-33 M.C.1.5 I-1 II-34 M.C.1.6 I-1 II-35 M.C.1.7 I-1 II-36M.C.1.8 I-1 II-37 M.C.1.9 I-1 II-38 M.C.1.10 I-1 II-39 M.C.1.11 I-1II-40 M.C.1.12 I-1 II-41 M.C.1.13 I-1 II-42 M.C.1.14 I-1 II-43 M.C.1.15I-1 II-44 M.C.1.16 I-1 II-45 M.C.1.17 I-1 II-46 M.C.1.18 I-1 II-47M.C.1.19 I-1 II-48 M.C.1.20 I-1 II-49 M.C.1.21 I-1 II-50 M.C.1.22 I-1II-51 M.C.1.23 I-1 II-52 M.C.1.24 I-1 II-53 M.C.1.25 I-1 II-54 M.C.1.26I-1 II-55 M.C.1.27 I-1 II-56 M.C.1.28 I-1 II-57 M.C.1.29 I-1 II-58

Table C2

Table C2 is as Table C1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.C.2.1 to M.C.2.29. Inthe context of the present invention, each of the rows of Table C2corresponds to one mixture.

Table C3

Table C3 is as Table C1, in which the compound I-1 is replaced bycompound 1-3, and the mixtures are named from M.C.3.1 to M.C.3.29. Inthe context of the present invention, each of the rows of Table C3corresponds to one mixture.

Table C4

Table C4A is as Table C1, in which the compound I-1 is replaced bycompound 1-4, and the mixtures are named from M.C.4.1 to M.C.4.29. Inthe context of the present invention, each of the rows of Table C4corresponds to one mixture.

Table C5

Table C5 is as Table C1, in which the compound I-1 is replaced bycompound 1-5, and the mixtures are named from M.C.5.1 to M.C.5.29. Inthe context of the present invention, each of the rows of Table C5corresponds to one mixture.

Table C6

Table C6 is as Table C1, in which the compound I-1 is replaced bycompound 1-6, and the mixtures are named from M.C.6.1 to M.C.6.29. Inthe context of the present invention, each of the rows of Table C6corresponds to one mixture.

Table C7

Table C7 is as Table C1, in which the compound I-1 is replaced bycompound 1-7, and the mixtures are named from M.C.7.1 to M.C.7.29. Inthe context of the present invention, each of the rows of Table C7corresponds to one mixture.

Table C8

Table C8 is as Table C1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.C.8.1 to M.C.8.29. Inthe context of the present invention, each of the rows of Table C8corresponds to one mixture.

Table C9

Table C9 is as Table C1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.C.9.1 to M.C.9.29. Inthe context of the present invention, each of the rows of Table C9corresponds to one mixture.

Table C10

Table C10 is as Table C1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.C.10.1 to M.C.10.29. Inthe context of the present invention, each of the rows of Table C10corresponds to one mixture.

Table C11

Table C11 is as Table C1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.C.11.1 to M.C.11.29. Inthe context of the present invention, each of the rows of Table C11corresponds to one mixture.

Table C12

Table C12 is as Table C1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.C.12.1 to M.C.12.29. Inthe context of the present invention, each of the rows of Table C12corresponds to one mixture.

All tables C are preferred embodiments of the present invention. WithinTable C1to Table C12, the following mixtures are preferred: M.C.1.3,M.C.1.4, M.C.1.7, M.C.1.15, M.C.1.20, M.C.1.21, M.C.1.23, M.C.1.27,M.C.2.3, M.C.2.4, M.C.2.7, M.C.2.15, M.C.2.20, M.C.2.21, M.C.2.23,M.C.2.27, M.C.3.3, M.C.3.4, M.C.3.7, M.C.3.15, M.C.3.20, M.C.3.21,M.C.3.23, M.C.3.27, M.C.4.3, M.C.4.4, M.C.4.7, M.C.4.15, M.C.4.20,M.C.4.21, M.C.4.23, M.C.4.27,

M.C.5.3, M.C.5.4, M.C.5.7, M.C.5.15, M.C.5.20, M.C.5.21, M.C.5.23,M.C.5.27, M.C.6.3, M.C.6.4, M.C.6.7, M.C.6.15, M.C.6.20, M.C.6.21,M.C.6.23, M.C.6.27, M.C.7.3, M.C.7.4, M.C.7.7, M.C.7.15, M.C.7.20,M.C.7.21, M.C.7.23, M.C.7.27, M.C.8.3, M.C.8.4, M.C.8.7, M.C.8.15,M.C.8.20, M.C.8.21, M.C.8.23, M.C.8.27, M.C.9.3, M.C.9.4, M.C.9.7,M.C.9.15, M.C.9.20, M.C.9.21, M.C.9.23, M.C.9.27, M.C.10.3, M.C.10.4,M.C.10.7, M.C.10.15, M.C.10.20, M.C.10.21, M.C.10.23, M.C.10.27,M.C.11.3, M.C.11.4, M.C.11.7, M.C.11.15, M.C.11.20, M.C.11.21,M.C.11.23, M.C.11.27, M.C.12.3, M.C.12.4, M.C.12.7, M.C.12.15,M.C.12.20, M.C.12.21, M.C.12.23 and M.C.12.27.

Within Table C1to Table C12, the following mixtures are more preferred:M.C.1.15,

M.C.2.15, M.C.3.15, M.C.4.15, M.C.5.15, M.C.6.15, M.C.7.15, M.C.8.15,M.C.9.15, M.C.10.15, M.C.11.15, M.C.12.15, M.C.1.20, M.C.2.20, M.C.3.20,M.C.4.20, M.C.5.20, M.C.6.20, M.C.7.20, M.C.8.20, M.C.9.20, M.C.10.20,M.C.11.20, M.C.12.20, M.C.1.21, M.C.2.21, M.C.3.21, M.C.4.21, M.C.5.21,M.C.6.21, M.C.7.21, M.C.8.21, M.C.9.21, M.C.10.21, M.C.11.21 andM.C.12.21.

TABLE D1 No I II M.D.1.1 I-1 II-59 M.D.1.2 I-1 II-60 M.D.1.3 I-1 II-61M.D.1.4 I-1 II-62 M.D.1.5 I-1 II-63 M.D.1.6 I-1 II-64

Table D2

Table D2 is as Table D1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.D.2.1 to M.D.2.6. In thecontext of the present invention, each of the rows of Table D2corresponds to one mixture.

Table D3

Table D3 is as Table D1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.D.3.1 to M.D.3.6. In thecontext of the present invention, each of the rows of Table D3corresponds to one mixture.

Table D4

Table D4A is as Table D1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.D.4.1 to M.D.4.6. In thecontext of the present invention, each of the rows of Table D4corresponds to one mixture.

Table D5

Table D5 is as Table D1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.D.5.1 to M.D.5.6. In thecontext of the present invention, each of the rows of Table D5corresponds to one mixture.

Table D6

Table D6 is as Table D1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.D.6.1 to M.D.6.6. In thecontext of the present invention, each of the rows of Table D6corresponds to one mixture.

Table D7

Table D7 is as Table D1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.D.7.1 to M.D.7.6. In thecontext of the present invention, each of the rows of Table D7corresponds to one mixture.

Table D8

Table D8 is as Table D1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.D.8.1 to M.D.8.6. In thecontext of the present invention, each of the rows of Table D8corresponds to one mixture.

Table D9

Table D9 is as Table D1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.D.9.1 to M.D.9.6. In thecontext of the present invention, each of the rows of Table D9corresponds to one mixture.

Table D10

Table D10 is as Table D1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.D.10.1 to M.D.10.6. Inthe context of the present invention, each of the rows of Table D10corresponds to one mixture.

Table D11

Table D11 is as Table D1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.D.11.1 to M.D.11.6. Inthe context of the present invention, each of the rows of Table D11corresponds to one mixture.

Table D12

Table D12 is as Table D1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.D.12.1 to M.D.12.6. Inthe context of the present invention, each of the rows of Table D12corresponds to one mixture.

All tables D are preferred embodiments of the present invention. WithinTable D1 to Table D12, the following mixtures are preferred: M.D.1.3,M.D.2.3, M.D.3.3, M.D.4.3, M.D.5.3, M.D.6.3, M.D.7.3, M.D.8.3, M.D.9.3,M.D.10.3, M.D.11.3, M.D.12.3, M.D.1.4, M.D.2.4, M.D.3.4, M.D.4.4,M.D.5.4, M.D.6.4, M.D.7.4, M.D.8.4, M.D.9.4, M.D.10.4, M.D.11.4,M.D.12.4, M.D.1.6, M.D.2.6, M.D.3.6, M.D.4.6, M.D.5.6, M.D.6.6, M.D.7.6,M.D.8.6, M.D.9.6, M.D.10.6, M.D.11.6 and M.D.12.6. Within Table D1 toTable D12, the following mixtures are more preferred: M.D.1.3, M.D.2.3,M.D.3.3, M.D.4.3, M.D.5.3, M.D.6.3, M.D.7.3, M.D.8.3, M.D.9.3, M.D.10.3,M.D.11.3, M.D.12.3, M.D.1.4, M.D.2.4, M.D.3.4, M.D.4.4, M.D.5.4,M.D.6.4, M.D.7.4, M.D.8.4, M.D.9.4, M.D.10.4, M.D.11.4, M.D.12.4,M.D.1.6, M.D.2.6, M.D.3.6, M.D.4.6, M.D.5.6, M.D.6.6, M.D.7.6, M.D.8.6,M.D.9.6, M.D.10.6, M.D.11.6 and M.D.12.6.

TABLE E1 Table E1 No I II M.F.1.1 I-1 II-65 M.F.1.2 I-1 II-66 M.F.1.3I-1 II-67 M.F.1.4 I-1 II-68 M.F.1.5 I-1 II-69

Table E2

Table E2 is as Table E1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.E.2.1 to M.E.2.5. In thecontext of the present invention, each of the rows of Table E2corresponds to one mixture.

Table E3

Table E3 is as Table E1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.E.3.1 to M.E.3.5. In thecontext of the present invention, each of the rows of Table E3corresponds to one mixture.

Table E4

Table E4A is as Table E1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.E.4.1 to M.E.4.5. In thecontext of the present invention, each of the rows of Table E4corresponds to one mixture.

Table E5

Table E5 is as Table E1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.E.5.1 to M.E.5.5. In thecontext of the present invention, each of the rows of Table E5corresponds to one mixture.

Table E6

Table E6 is as Table E1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.E.6.1 to M.E.6.5. In thecontext of the present invention, each of the rows of Table E6corresponds to one mixture.

Table E7

Table E7 is as Table E1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.E.7.1 to M.E.7.5. In thecontext of the present invention, each of the rows of Table E7corresponds to one mixture.

Table E8

Table E8 is as Table E1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.E.8.1 to M.E.8.5. In thecontext of the present invention, each of the rows of Table E8corresponds to one mixture.

Table E9

Table E9 is as Table E1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.E.9.1 to M.E.9.5. In thecontext of the present invention, each of the rows of Table E9corresponds to one mixture.

Table E10

Table E10 is as Table E1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.E.10.1 to M.E.10.5. Inthe context of the present invention, each of the rows of Table E10corresponds to one mixture.

Table E1

Table E11is as Table E1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.E.11.1 to M.E.11.5. Inthe context of the present invention, each of the rows of TableE11corresponds to one mixture.

Table E12

Table E12 is as Table E1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.E.12.1 to M.E.12.5. Inthe context of the present invention, each of the rows of Table E12corresponds to one mixture.

All tables E are preferred embodiments of the present invention. WithinTable E1to Table E12, the following mixtures are preferred: M.E.1.5,M.E.2.5, M.E.3.5, M.E.4.5, M.E.5.5,

M.E.6.5, M.E.7.5, M.E.8.5, M.E.9.5, M.E.10.5, M.E.11.5 and M.E.12.5.

TABLE F1 Table F1 No I II M.F.1.1 I-1 II-70 M.F.1.2 I-1 II-71 M.F.1.3I-1 II-72 M.F.1.4 I-1 II-73 M.F.1.5 I-1 II-74 M.F.1.6 I-1 II-75 M.F.1.7I-1 II-76

Table F2

Table F2 is as Table F1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.F.2.1 to M.F.2.7. In thecontext of the present invention, each of the rows of Table F2corresponds to one mixture.

Table F3

Table F3 is as Table F1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.F.3.1 to M.F.3.7. In thecontext of the present invention, each of the rows of Table F3corresponds to one mixture.

Table F4

Table F4A is as Table F1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.F.4.1 to M.F.4.7. In thecontext of the present invention, each of the rows of Table F4corresponds to one mixture.

Table F5

Table F5 is as Table F1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.F.5.1 to M.F.5.7. In thecontext of the present invention, each of the rows of Table F5corresponds to one mixture.

Table F6

Table F6 is as Table F1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.F.6.1 to M.F.6.7. In thecontext of the present invention, each of the rows of Table F6corresponds to one mixture.

Table F7

Table F7 is as Table F1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.F.7.1 to M.F.7.7. In thecontext of the present invention, each of the rows of Table F7corresponds to one mixture.

Table F8

Table F8 is as Table F1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.F.8.1 to M.F.8.7. In thecontext of the present invention, each of the rows of Table F8corresponds to one mixture.

Table F9

Table F9 is as Table F1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.F.9.1 to M.F.9.7. In thecontext of the present invention, each of the rows of Table F9corresponds to one mixture.

Table F10

Table F10 is as Table F1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.F.10.1 to M.F.10.7. Inthe context of the present invention, each of the rows of Table F10corresponds to one mixture.

Table F11

Table F11 is as Table F1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.F.11.1 to M.F.11.7. Inthe context of the present invention, each of the rows of Table F11corresponds to one mixture.

Table F12

Table F12 is as Table F1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.F.12.1 to M.F.12.7. Inthe context of the present invention, each of the rows of Table F12corresponds to one mixture.

All tables F are preferred embodiments of the present invention. WithinTable F1 to Table F12, the following mixtures are preferred:

M.F.1.7, M.F.1.6, M.F.2.7, M.F.2.6, M.F.3.7, M.F.3.6, M.F.4.7, M.F.4.6,M.F.5.7, M.F.5.6, M.F.6.7, M.F.6.7, M.F.7.6, M.F.7.7, M.F.8.6, M.F.8.7,M.F.9.6, M.F.9.7, M.F.10.6, M.F.10.7, M.F.11.6, M.F.11.7, M.F.12.6 andM.F.12.7.

Within Table F1 to Table F12, the following mixtures are more preferred:

M.F.1.7, M.F.2.7, M.F.3.7, M.F.4.7, M.F.5.7, M.F.6.7, M.F.7.7, M.F.8.7,M.F.9.7, M.F.10.7, M.F.11.7 and M.F.12.7.

TABLE G1 No I II M.G.1.1 I-1 II-77 M.G.1.2 I-1 II-78 M.G.1.3 I-1 II-79M.G.1.4 I-1 II-80 M.G.1.5 I-1 II-81 M.G.1.6 I-1 II-82 M.G.1.7 I-1 II-83M.G.1.8 I-1 II-84 M.G.1.9 I-1 II-85 M.G.1.10 I-1 II-86 M.G.1.11 I-1II-87 M.G.1.12 I-1 II-88 M.G.1.13 I-1 II-89 M.G.1.14 I-1 II-90 M.G.1.15I-1 II-91 M.G.1.16 I-1 II-92 M.G.1.17 I-1 II-93 M.G.1.18 I-1 II-94M.G.1.19 I-1 II-95 M.G.1.20 I-1 II-96 M.G.1.21 I-1 II-97 M.G.1.22 I-1II-98

Table G2

Table G2 is as Table G1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.G.2.1 to M.G.2.22. Inthe context of the present invention, each of the rows of Table G2corresponds to one mixture.

Table G3

Table G3 is as Table G1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.G.3.1 to M.G.3.22. Inthe context of the present invention, each of the rows of Table G3corresponds to one mixture.

Table G4

Table G4A is as Table G1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.G.4.1 to M.G.4.22. Inthe context of the present invention, each of the rows of Table G4corresponds to one mixture.

Table G5

Table G5 is as Table G1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.G.5.1 to M.G.5.22. Inthe context of the present invention, each of the rows of Table G5corresponds to one mixture.

Table G6

Table G6 is as Table G1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.G.6.1 to M.G.6.22. Inthe context of the present invention, each of the rows of Table G6corresponds to one mixture.

Table G7

Table G7 is as Table G1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.G.7.1 to M.G.7.22. Inthe context of the present invention, each of the rows of Table G7corresponds to one mixture.

Table G8

Table G8 is as Table G1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.G.8.1 to M.G.8.22. Inthe context of the present invention, each of the rows of Table G8corresponds to one mixture.

Table G9

Table G9 is as Table G1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.G.9.1 to M.G.9.22. Inthe context of the present invention, each of the rows of Table G9corresponds to one mixture.

Table G10

Table G10 is as Table G1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.G.10.1 to M.G.10.22. Inthe context of the present invention, each of the rows of Table G10corresponds to one mixture.

Table G11

Table G11 is as Table G1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.G.11.1 to M.G.11.22. Inthe context of the present invention, each of the rows of Table G11corresponds to one mixture.

Table G12

Table G12 is as Table G1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.G.12.1 to M.G.12.22. Inthe context of the present invention, each of the rows of Table G12corresponds to one mixture.

All tables G are preferred embodiments of the present invention. WithinTable G1 to Table G12, the following mixtures are preferred: M.G.1.7,M.G.2.7, M.G.3.7, M.G.4.7, M.G.5.7, M.G.6.7, M.G.7.7, M.G.8.7, M.G.9.7,M.G.10.7, M.G.11.7, M.G.12.7, M.G.1.15, M.G.2.15, M.G.3.15, M.G.4.15,M.G.5.15, M.G.6.15, M.G.7.15, M.G.8.15, M.G.9.15, M.G.10.15, M.G.11.15,M.G.12.15, M.G.1.22, M.G.2.22, M.G.3.22, M.G.4.22, M.G.5.22, M.G.6.22,M.G.7.22, M.G.8.22, M.G.9.22, M.G.10.22, M.G.11.22 and M.G.12.22.

Within Table G1 to Table G12, the following mixtures are more preferred:M.G.1.15, M.G.2.15, M.G.3.15, M.G.4.15, M.G.5.15, M.G.6.15, M.G.7.15,M.G.8.15, M.G.9.15, M.G.10.15, M.G.11.15 and M.G.12.15.

TABLE H1 Table H1 No I II M.H.1.1 II-1 II-99 M.H.1.2 II-1 II-100 M.H.1.3II-1 II-101 M.H.1.4 II-1 II-102 M.H.1.5 II-1 II-103 M.H.1.6 II-1 II-104M.H.1.7 II-1 II-105 M.H.1.8 II-1 II-106 M.H.1.9 II-1 II-107 M.H.1.10II-1 II-108 M.H.1.11 II-1 II-109 M.H.1.12 II-1 II-110 M.H.1.13 II-1II-111 M.H.1.14 II-1 II-112 M.H.1.15 II-1 II-113 M.H.1.16 II-1 II-114M.H.1.17 II-1 II-115 M.H.1.18 II-1 II-116 M.H.1.19 II-1 II-117 M.H.1.20II-1 II-118 M.H.1.21 II-1 II-119 M.H.1.22 II-1 II-120 M.H.1.23 II-1II-121 M.H.1.24 II-1 II-122 M.H.1.25 II-1 II-123 M.H.1.26 II-1 II-124M.H.1.27 II-1 II-125 M.H.1.28 II-1 II-126 M.H.1.29 II-1 II-127 M.H.1.30II-1 II-128 M.H.1.31 II-1 II-129 M.H.1.32 II-1 II-130 M.H.1.33 II-1II-131 M.H.1.34 II-1 II-132 M.H.1.35 II-1 II-133 M.H.1.36 II-1 II-134M.H.1.37 II-1 II-135 M.H.1.38 II-1 II-136 M.H.1.39 II-1 II-137 M.H.1.40II-1 II-138 M.H.1.41 II-1 II-139 M.H.1.42 II-1 II-140 M.H.1.43 II-1II-141 M.H.1.44 II-1 II-142 M.H.1.45 II-1 II-143 M.H.1.46 II-1 II-144M.H.1.47 II-1 II-145 M.H.1.48 II-1 II-146 M.H.1.49 II-1 II-147 M.H.1.50II-1 II-148 M.H.1.51 II-1 II-149 M.H.1.52 II-1 II-150 M.H.1.53 II-1II-151 M.H.1.54 II-1 II-152 M.H.1.55 II-1 II-153 M.H.1.56 II-1 II-154M.H.1.57 II-1 II-155 M.H.1.58 II-1 II-156 M.H.1.59 II-1 II-157 M.H.1.60II-1 II-158 M.H.1.61 II-1 II-159 M.H.1.62 II-1 II-160 M.H.1.63 II-1II-161 M.H.1.64 II-1 II-162 M.H.1.65 II-1 II-163 M.H.1.66 II-1 II-164M.H.1.67 II-1 II-165 M.H.1.68 II-1 II-166 M.H.1.69 II-1 II-167 M.H.1.70II-1 II-168 M.H.1.71 II-1 II-169 M.H.1.72 II-1 II-170 M.H.1.73 II-1II-171 M.H.1.74 II-1 II-172 M.H.1.75 II-1 II-173 M.H.1.76 II-1 II-174M.H.1.77 II-1 II-175 M.H.1.78 II-1 II-176 M.H.1.79 II-1 II-177 M.H.1.80II-1 II-178 M.H.1.81 II-1 II-179 M.H.1.82 II-1 II-180 M.H.1.83 II-1II-181 M.H.1.84 II-1 II-182 M.H.1.85 II-1 II-183 M.H.1.86 II-1 II-184M.H.1.87 II-1 II-185 M.H.1.88 II-1 II-186 M.H.1.89 II-1 II-187 M.H.1.90II-1 II-188 M.H.1.91 II-1 II-189 M.H.1.92 II-1 II-190 M.H.1.93 II-1II-191

Table H2

Table H2 is as Table H1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.H.2.1 to M.H.2.93. Inthe context of the present invention, each of the rows of Table H2corresponds to one mixture.

Table H3

Table H3 is as Table H1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.H.3.1 to M.H.3.93. Inthe context of the present invention, each of the rows of Table H3corresponds to one mixture.

Table H4

Table H4A is as Table H1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.H.4.1 to M.H.4.93. Inthe context of the present invention, each of the rows of Table H4corresponds to one mixture.

Table H5

Table H5 is as Table H1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.H.5.1 to M.H.5. 93. Inthe context of the present invention, each of the rows of Table H5corresponds to one mixture.

Table H6

Table H6 is as Table H1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.H.6.1 to M.H.6.93. Inthe context of the present invention, each of the rows of Table H6corresponds to one mixture.

Table H7

Table H7 is as Table H1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.H.7.1 to M.H.7.93. Inthe context of the present invention, each of the rows of Table H7corresponds to one mixture.

Table H8

Table H8 is as Table H1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.H.8.1 to M.H.8.93. Inthe context of the present invention, each of the rows of Table H8corresponds to one mixture.

Table H9

Table H9 is as Table H1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.H.9.1 to M.H.9.93. Inthe context of the present invention, each of the rows of Table H9corresponds to one mixture.

Table H10

Table H10 is as Table H1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.H.10.1 to M.H.10.93. Inthe context of the present invention, each of the rows of Table H10corresponds to one mixture.

Table H11

Table H11 is as Table H1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.H.11.1 to M.H.11.93. Inthe context of the present invention, each of the rows of Table H11corresponds to one mixture.

Table H12

Table H12 is as Table H1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.H.12.1 to M.H.12.93. Inthe context of the present invention, each of the rows of Table H12corresponds to one mixture.

The invention also relates to the ternary mixtures comprising onecompound land two compunds II. In particular, the present inventionrelates to the ternary mixtures set forth in Table Z.

Within Table Z, the following abbreviations are used:

azoxystrobin (IIa-1); kresoxim-methyl (IIa-2); mandestrobin (IIa-3)metaminostrobin (IIa-4); picoxystrobin (IIa-5); pyraclostrobin (IIa-6)trifloxystrobin (IIa-7); benzovindiflupyr (IIb-1); bixafen (IIb-2)boscalid (IIb-3); fluopyram (IIb-4); fluxapyroxad (IIb-5) 3(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl¬indan-4-yl)pyrazole-4-carboxamide(IIb-6) 3(trifluoromethyl)-1-methyl-N-(1,1,3-trimethyl¬indan-4-yl)pyrazole-4-carboxamide(IIb-7)1,3-dimethyl-N-(1,1,3-trimethylindan-4-yl)pyr¬azole-4-carboxamide(IIb-8)3-(trifluorometh-yl)-1,5-dimethyl-N-(1,1,3-trimethylindan-4-yl)¬pyrazole-4-carboxamide(IIb-9)1,3,5-tri-methyl-N-(1,1,3-trimethylindan-4-yl)pyrazole-4¬car-iboxamide(IIb-10) cyproconazole (IIc-1); difenoconazole (IIc-2); epoxiconazole(IIc-3); metconazole (IIc-4); propiconazole (IIc-5); prothioconazole(IIc-6); tebuconazole (IIc-7); triticonazole (IIc-8); fenpropimorph(IId-1); fenpropidin (IId-2); spiroxamine (IId-3); mancozeb, (IIe-1);chlorothalonil, (IIe-2);2,6-di-methyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c′]dipyrrole-1,3,5,7(2H,6H)-tetraone(IIe-3) thiophanate-methyl (IIf-1) metrafenone (IIf-2) pyriofenone(IIf-3) “I” means compound I, “II(1) means the first “II(1)” means thesecond compound II.

The present invention therefore relates to the following ternarymixtures:

TABLE Z1 No I 11 (1) II (2) M.Z.1.1 I-1 11a-1 IIb-1 M.Z.1.2 I-1 IIa-1IIb-2 M.Z.1.3 I-1 IIa-1 IIb-3 M.Z.1.4 I-1 IIa-1 IIb-4 M.Z.1.5 I-1 IIa-1IIb-5 M.Z.1.6 I-1 IIa-1 IIb-6 M.Z.1.7 I-1 IIa-2 IIb-1 M.Z.1.8 I-1 IIa-2IIb-2 M.Z.1.9 I-1 IIa-2 IIb-3 M.Z.1.10 I-1 IIa-2 IIb-4 M.Z.1.11 I-1IIa-2 IIb-5 M.Z.1.12 I-1 IIa-2 IIb-6 M.Z.1.13 I-1 IIa-2 IIb-7 M.Z.1.14I-1 IIa-2 IIb-8 M.Z.1.15 I-1 IIa-2 IIb-9 M.Z.1.16 I-1 IIa-2 IIb-10M.Z.1.17 I-1 IIa-3 IIb-1 M.Z.1.18 I-1 IIa-3 IIb-2 M.Z.1.19 I-1 IIa-3IIb-3 M.Z.1.20 I-1 IIa-3 IIb-4 M.Z.1.21 I-1 IIa-3 IIb-5 M.Z.1.22 I-1IIa-3 IIb-6 M.Z.1.23 I-1 IIa-3 IIb-7 M.Z.1.24 I-1 IIa-3 IIb-8 M.Z.1.25I-1 IIa-3 IIb-9 M.Z.1.26 I-1 IIa-3 IIb-10 M.Z.1.27 I-1 IIa-4 IIb-1M.Z.1.28 I-1 IIa-4 IIb-2 M.Z.1.29 I-1 IIa-4 IIb-3 M.Z.1.30 I-1 IIa-4IIb-4 M.Z.1.31 I-1 IIa-4 IIb-5 M.Z.1.32 I-1 IIa-4 IIb-6 M.Z.1.33 I-1IIa-4 IIb-7 M.Z.1.34 I-1 IIa-4 IIb-8 M.Z.1.35 I-1 IIa-4 IIb-9 M.Z.1.36I-1 IIa-4 IIb-10 M.Z.1.37 I-1 IIa-5 IIb-1 M.Z.1.38 I-1 IIa-5 IIb-2M.Z.1.39 I-1 IIa-5 IIb-3 M.Z.1.40 I-1 IIa-5 IIb-4 M.Z.1.41 I-1 IIa-5IIb-5 M.Z.1.42 I-1 IIa-5 IIb-6 M.Z.1.43 I-1 IIa-5 IIb-7 M.Z.1.44 I-1IIa-5 IIb-8 M.Z.1.45 I-1 IIa-5 IIb-9 M.Z.1.46 I-1 IIa-5 IIb-10 M.Z.1.47I-1 IIa-6 IIb-1 M.Z.1.48 I-1 IIa-6 IIb-2 M.Z.1.49 I-1 IIa-6 IIb-3M.Z.1.50 I-1 IIa-6 IIb-4 M.Z.1.51 I-1 IIa-6 IIb-5 M.Z.1.52 I-1 IIa-6IIb-6 M.Z.1.53 I-1 IIa-6 IIb-7 M.Z.1.54 I-1 IIa-6 IIb-8 M.Z.1.55 I-1IIa-6 IIb-9 M.Z.1.56 I-1 IIa-6 IIb-10 M.Z.1.57 I-1 IIa-7 IIb-1 M.Z.1.58I-1 IIa-7 IIb-2 M.Z.1.59 I-1 IIa-7 IIb-3 M.Z.1.60 I-1 IIa-7 IIb-4M.Z.1.61 I-1 IIa-7 IIb-5 M.Z.1.62 I-1 IIa-7 IIb-6 M.Z.1.63 I-1 IIa-7IIb-7 M.Z.1.64 I-1 IIa-7 IIb-8 M.Z.1.65 I-1 IIa-7 IIb-9 M.Z.1.66 I-1IIa-7 IIb-10 M.Z.1.67 I-1 IIa-1 IIc-1 M.Z.1.68 I-1 IIa-1 IIc-2 M.Z.1.69I-1 IIa-1 IIc-3 M.Z.1.70 I-1 IIa-1 IIc-4 M.Z.1.71 I-1 IIa-1 IIc-5M.Z.1.72 I-1 IIa-1 IIc-6 M.Z.1.73 I-1 IIa-1 IIc-7 M.Z.1.74 I-1 IIa-1IIc-8 M.Z.1.75 I-1 IIa-2 IIc-1 M.Z.1.76 I-1 IIa-2 IIc-2 M.Z.1.77 I-1IIa-2 IIc-3 M.Z.1.78 I-1 IIa-2 IIc-4 M.Z.1.79 I-1 IIa-2 IIc-5 M.Z.1.80I-1 IIa-2 IIc-6 M.Z.1.81 I-1 IIa-2 IIc-7 M.Z.1.82 I-1 IIa-2 IIc-8M.Z.1.83 I-1 IIa-3 IIc-1 M.Z.1.84 I-1 IIa-3 IIc-2 M.Z.1.85 I-1 IIa-3IIc-3 M.Z.1.86 I-1 IIa-3 IIc-4 M.Z.1.87 I-1 IIa-3 IIc-5 M.Z.1.88 I-1IIa-3 IIc-6 M.Z.1.89 I-1 IIa-3 IIc-7 M.Z.1.90 I-1 IIa-3 IIc-8 M.Z.1.91I-1 IIa-4 IIc-1 M.Z.1.92 I-1 IIa-4 IIc-2 M.Z.1.93 I-1 IIa-4 IIc-3M.Z.1.94 I-1 IIa-4 IIc-4 M.Z.1.95 I-1 IIa-4 IIc-5 M.Z.1.96 I-1 IIa-4IIc-6 M.Z.1.97 I-1 IIa-4 IIc-7 M.Z.1.98 I-1 IIa-4 IIc-8 M.Z.1.99 I-1IIa-5 IIc-1 M.Z.1.100 I-1 IIa-5 IIc-2 M.Z.1.101 I-1 IIa-5 IIc-3M.Z.1.102 I-1 IIa-5 IIc-4 M.Z.1.103 I-1 IIa-5 IIc-5 M.Z.1.104 I-1 IIa-5IIc-6 M.Z.1.105 I-1 IIa-5 IIc-7 M.Z.1.106 I-1 IIa-5 IIc-8 M.Z.1.107 I-1IIa-6 IIc-1 M.Z.1.108 I-1 IIa-6 IIc-2 M.Z.1.109 I-1 IIa-6 IIc-3M.Z.1.110 I-1 IIa-6 IIc-4 M.Z.1.111 I-1 IIa-6 IIc-5 M.Z.1.112 I-1 IIa-6IIc-6 M.Z.1.113 I-1 IIa-6 IIc-7 M.Z.1.114 I-1 IIa-6 IIc-8 M.Z.1.115 I-1IIa-7 IIc-1 M.Z.1.116 I-1 IIa-7 IIc-2 M.Z.1.117 I-1 IIa-7 IIc-3M.Z.1.118 I-1 IIa-7 IIc-4 M.Z.1.119 I-1 IIa-7 IIc-5 M.Z.1.120 I-1 IIa-7IIc-6 M.Z.1.121 I-1 IIa-7 IIc-7 M.Z.1.122 I-1 IIa-7 IIc-8 M.Z.1.123 I-1IIa-1 IId-1 M.Z.1.124 I-1 IIa-1 IId-2 M.Z.1.125 I-1 IIa-1 IId-3M.Z.1.126 I-1 IIa-2 IId-1 M.Z.1.127 I-1 IIa-2 IId-2 M.Z.1.128 I-1 IIa-2IId-3 M.Z.1.129 I-1 IIa-3 IId-1 M.Z.1.130 I-1 IIa-3 IId-2 M.Z.1.131 I-1IIa-3 IId-3 M.Z.1.132 I-1 IIa-4 IId-1 M.Z.1.133 I-1 IIa-4 IId-2M.Z.1.134 I-1 IIa-4 IId-3 M.Z.1.135 I-1 IIa-5 IId-1 M.Z.1.136 I-1 IIa-5IId-2 M.Z.1.137 I-1 IIa-5 IId-3 M.Z.1.138 I-1 IIa-6 IId-1 M.Z.1.139 I-1IIa-6 IId-2 M.Z.1.140 I-1 IIa-6 IId-3 M.Z.1.141 I-1 IIa-7 IId-1M.Z.1.142 I-1 IIa-7 IId-2 M.Z.1.143 I-1 IIa-7 IId-3 M.Z.1.144 I-1 IIa-1IIe-1 M.Z.1.145 I-1 IIa-1 IIe-2 M.Z.1.146 I-1 IIa-1 IIe-3 M.Z.1.147 I-1IIa-2 IIe-1 M.Z.1.148 I-1 IIa-2 IIe-2 M.Z.1.149 I-1 IIa-2 IIe-3M.Z.1.150 I-1 IIa-3 IIe-1 M.Z.1.151 I-1 IIa-3 IIe-2 M.Z.1.152 I-1 IIa-3IIe-3 M.Z.1.153 I-1 IIa-4 IIe-1 M.Z.1.154 I-1 IIa-4 IIe-2 M.Z.1.155 I-1IIa-4 IIe-3 M.Z.1.156 I-1 IIa-5 IIe-1 M.Z.1.157 I-1 IIa-5 IIe-2M.Z.1.158 I-1 IIa-5 IIe-3 M.Z.1.159 I-1 IIa-6 IIe-1 M.Z.1.160 I-1 IIa-6IIe-2 M.Z.1.161 I-1 IIa-6 IIe-3 M.Z.1.162 I-1 IIa-7 IIe-1 M.Z.1.163 I-1IIa-7 IIe-2 M.Z.1.164 I-1 IIa-7 IIe-3 M.Z.1.165 I-1 IIa-1 IIf-1M.Z.1.166 I-1 IIa-1 IIf-2 M.Z.1.167 I-1 IIa-1 IIf-3 M.Z.1.168 I-1 IIa-2IIf-1 M.Z.1.169 I-1 IIa-2 IIf-2 M.Z.1.170 I-1 IIa-2 IIf-3 M.Z.1.171 I-1IIa-3 IIf-1 M.Z.1.172 I-1 IIa-3 IIf-2 M.Z.1.173 I-1 IIa-3 IIf-3M.Z.1.174 I-1 IIa-4 IIf-1 M.Z.1.175 I-1 IIa-4 IIf-2 M.Z.1.176 I-1 IIa-4IIf-3 M.Z.1.177 I-1 IIa-5 IIf-1 M.Z.1.178 I-1 IIa-5 IIf-2 M.Z.1.179 I-1IIa-5 IIf-3 M.Z.1.180 I-1 IIa-6 IIf-1 M.Z.1.181 I-1 IIa-6 IIf-2M.Z.1.182 I-1 IIa-6 IIf-3 M.Z.1.183 I-1 IIa-7 IIf-1 M.Z.1.184 I-1 IIa-7IIf-2 M.Z.1.185 I-1 IIa-7 IIf-3 M.Z.1.186 I-1 IIb-1 IIc-1 M.Z.1.187 I-1IIb-1 IIc-2 M.Z.1.188 I-1 IIb-1 IIc-3 M.Z.1.189 I-1 IIb-1 IIc-4M.Z.1.190 I-1 IIb-1 IIc-5 M.Z.1.191 I-1 IIb-1 IIc-6 M.Z.1.192 I-1 IIb-1IIc-7 M.Z.1.193 I-1 IIb-1 IIc-8 M.Z.1.194 I-1 IIb-2 IIc-1 M.Z.1.195 I-1IIb-2 IIc-2 M.Z.1.196 I-1 IIb-2 IIc-3 M.Z.1.197 I-1 IIb-2 IIc-4M.Z.1.198 I-1 IIb-2 IIc-5 M.Z.1.199 I-1 IIb-2 IIc-6 M.Z.1.200 I-1 IIb-2IIc-7 M.Z.1.201 I-1 IIb-2 IIc-8 M.Z.1.202 I-1 IIb-3 IIc-1 M.Z.1.203 I-1IIb-3 IIc-2 M.Z.1.204 I-1 IIb-3 IIc-3 M.Z.1.205 I-1 IIb-3 IIc-4M.Z.1.206 I-1 IIb-3 IIc-5 M.Z.1.207 I-1 IIb-3 IIc-6 M.Z.1.208 I-1 IIb-3IIc-7 M.Z.1.209 I-1 IIb-3 IIc-8 M.Z.1.210 I-1 IIb-4 IIc-1 M.Z.1.211 I-1IIb-4 IIc-2 M.Z.1.212 I-1 IIb-4 IIc-3 M.Z.1.213 I-1 IIb-4 IIc-4M.Z.1.214 I-1 IIb-4 IIc-5 M.Z.1.215 I-1 IIb-4 IIc-6 M.Z.1.216 I-1 IIb-4IIc-7 M.Z.1.217 I-1 IIb-4 IIc-8 M.Z.1.218 I-1 IIb-5 IIc-1 M.Z.1.219 I-1IIb-5 IIc-2 M.Z.1.220 I-1 IIb-5 IIc-3 M.Z.1.221 I-1 IIb-5 IIc-4M.Z.1.222 I-1 IIb-5 IIc-5 M.Z.1.223 I-1 IIb-5 IIc-6 M.Z.1.224 I-1 IIb-5IIc-7 M.Z.1.225 I-1 IIb-5 IIc-8 M.Z.1.226 I-1 IIb-6 IIc-1 M.Z.1.227 I-1IIb-6 IIc-2 M.Z.1.228 I-1 IIb-6 IIc-3 M.Z.1.229 I-1 IIb-6 IIc-4M.Z.1.230 I-1 IIb-6 IIc-5 M.Z.1.231 I-1 IIb-6 IIc-6 M.Z.1.232 I-1 IIb-6IIc-7 M.Z.1.233 I-1 IIb-6 IIc-8 M.Z.1.234 I-1 IIb-7 IIc-1 M.Z.1.235 I-1IIb-7 IIc-2 M.Z.1.236 I-1 IIb-7 IIc-3 M.Z.1.237 I-1 IIb-7 IIc-4M.Z.1.238 I-1 IIb-7 IIc-5 M.Z.1.239 I-1 IIb-7 IIc-6 M.Z.1.240 I-1 IIb-7IIc-7 M.Z.1.241 I-1 IIb-7 IIc-8 M.Z.1.242 I-1 IIb-8 IIc-1 M.Z.1.243 I-1IIb-8 IIc-2 M.Z.1.244 I-1 IIb-8 IIc-3 M.Z.1.245 I-1 IIb-8 IIc-4M.Z.1.246 I-1 IIb-8 IIc-5 M.Z.1.247 I-1 IIb-8 IIc-6 M.Z.1.248 I-1 IIb-8IIc-7 M.Z.1.249 I-1 IIb-8 IIc-8 M.Z.1.250 I-1 IIb-9 IIc-1 M.Z.1.251 I-1IIb-9 IIc-2 M.Z.1.252 I-1 IIb-9 IIc-3 M.Z.1.253 I-1 IIb-9 IIc-4M.Z.1.254 I-1 IIb-9 IIc-5 M.Z.1.255 I-1 IIb-9 IIc-6 M.Z.1.256 I-1 IIb-9IIc-7 M.Z.1.257 I-1 IIb-9 IIc-8 M.Z.1.258 I-1 IIb-10 IIc-1 M.Z.1.259 I-1IIb-10 IIc-2 M.Z.1.260 I-1 IIb-10 IIc-3 M.Z.1.261 I-1 IIb-10 IIc-4M.Z.1.262 I-1 IIb-10 IIc-5 M.Z.1.263 I-1 IIb-10 IIc-6 M.Z.1.264 I-1IIb-10 IIc-7 M.Z.1.265 I-1 IIb-10 IIc-8 M.Z.1.266 I-1 IIb-1 IId-1M.Z.1.267 I-1 IIb-1 IId-2 M.Z.1.268 I-1 IIb-1 IId-3 M.Z.1.269 I-1 IIb-2IId-1 M.Z.1.270 I-1 IIb-2 IId-2 M.Z.1.271 I-1 IIb-2 IId-3 M.Z.1.272 I-1IIb-3 IId-1 M.Z.1.273 I-1 IIb-3 IId-2 M.Z.1.274 I-1 IIb-3 IId-3M.Z.1.275 I-1 IIb-4 IId-1 M.Z.1.276 I-1 IIb-4 IId-2 M.Z.1.277 I-1 IIb-4IId-3 M.Z.1.278 I-1 IIb-5 IId-1 M.Z.1.279 I-1 IIb-5 IId-2 M.Z.1.280 I-1IIb-5 IId-3 M.Z.1.281 I-1 IIb-6 IId-1 M.Z.1.282 I-1 IIb-6 IId-2M.Z.1.283 I-1 IIb-6 IId-3 M.Z.1.284 I-1 IIb-7 IId-1 M.Z.1.285 I-1 IIb-7IId-2 M.Z.1.286 I-1 IIb-7 IId-3 M.Z.1.287 I-1 IIb-8 IId-1 M.Z.1.288 I-1IIb-8 IId-2 M.Z.1.289 I-1 IIb-8 IId-3 M.Z.1.290 I-1 IIb-9 IId-1M.Z.1.291 I-1 IIb-9 IId-2 M.Z.1.292 I-1 IIb-9 IId-3 M.Z.1.293 I-1 IIb-10IId-1 M.Z.1.294 I-1 IIb-10 IId-2 M.Z.1.295 I-1 IIb-10 IId-3 M.Z.1.296I-1 IIb-1 IIe-1 M.Z.1.297 I-1 IIb-1 IIe-2 M.Z.1.298 I-1 IIb-1 IIe-3M.Z.1.299 I-1 IIb-2 IIe-1 M.Z.1.300 I-1 IIb-2 IIe-2 M.Z.1.301 I-1 IIb-2IIe-3 M.Z.1.302 I-1 IIb-3 IIe-1 M.Z.1.303 I-1 IIb-3 IIe-2 M.Z.1.304 I-1IIb-3 IIe-3 M.Z.1.305 I-1 IIb-4 IIe-1 M.Z.1.306 I-1 IIb-4 IIe-2M.Z.1.307 I-1 IIb-4 IIe-3 M.Z.1.308 I-1 IIb-5 IIe-1 M.Z.1.309 I-1 IIb-5IIe-2 M.Z.1.310 I-1 IIb-5 IIe-3 M.Z.1.311 I-1 IIb-6 IIe-1 M.Z.1.312 I-1IIb-6 IIe-2 M.Z.1.313 I-1 IIb-6 IIe-3 M.Z.1.314 I-1 IIb-7 IIe-1M.Z.1.315 I-1 IIb-7 IIe-2 M.Z.1.316 I-1 IIb-7 IIe-3 M.Z.1.317 I-1 IIb-8IIe-1 M.Z.1.318 I-1 IIb-8 IIe-2 M.Z.1.319 I-1 IIb-8 IIe-3 M.Z.1.320 I-1IIb-9 IIe-1 M.Z.1.321 I-1 IIb-9 IIe-2 M.Z.1.322 I-1 IIb-9 IIe-3M.Z.1.323 I-1 IIb-10 IIe-1 M.Z.1.324 I-1 IIb-10 IIe-2 M.Z.1.325 I-1IIb-10 IIe-3 M.Z.1.326 I-1 IIb-1 IIf-1 M.Z.1.327 I-1 IIb-1 IIf-2M.Z.1.328 I-1 IIb-1 IIf-3 M.Z.1.329 I-1 IIb-2 IIf-1 M.Z.1.330 I-1 IIb-2IIf-2 M.Z.1.331 I-1 IIb-2 IIf-3 M.Z.1.332 I-1 IIb-3 IIf-1 M.Z.1.333 I-1IIb-3 IIf-2 M.Z.1.334 I-1 IIb-3 IIf-3 M.Z.1.335 I-1 IIb-4 IIf-1M.Z.1.336 I-1 IIb-4 IIf-2 M.Z.1.337 I-1 IIb-4 IIf-3 M.Z.1.338 I-1 IIb-5IIf-1 M.Z.1.339 I-1 IIb-5 IIf-2 M.Z.1.340 I-1 IIb-5 IIf-3 M.Z.1.341 I-1IIb-6 IIf-1 M.Z.1.342 I-1 IIb-6 IIf-2 M.Z.1.343 I-1 IIb-6 IIf-3M.Z.1.344 I-1 IIb-7 IIf-1 M.Z.1.345 I-1 IIb-7 IIf-2 M.Z.1.346 I-1 IIb-7IIf-3 M.Z.1.347 I-1 IIb-8 IIf-1 M.Z.1.348 I-1 IIb-8 IIf-2 M.Z.1.349 I-1IIb-8 IIf-3 M.Z.1.350 I-1 IIb-9 IIf-1 M.Z.1.351 I-1 IIb-9 IIf-2M.Z.1.352 I-1 IIb-9 IIf-3 M.Z.1.353 I-1 IIb-10 IIf-1 M.Z.1.354 I-1IIb-10 IIf-2 M.Z.1.355 I-1 IIb-10 IIf-3 M.Z.1.356 I-1 IIc-1 IId-1M.Z.1.357 I-1 IIc-1 IId-2 M.Z.1.358 I-1 IIc-1 IId-3 M.Z.1.359 I-1 IIc-2IId-1 M.Z.1.360 I-1 IIc-2 IId-2 M.Z.1.361 I-1 IIc-2 IId-3 M.Z.1.362 I-1IIc-3 IId-1 M.Z.1.363 I-1 IIc-3 IId-2 M.Z.1.364 I-1 IIc-3 IId-3M.Z.1.365 I-1 IIc-4 IId-1 M.Z.1.366 I-1 IIc-4 IId-2 M.Z.1.367 I-1 IIc-4IId-3 M.Z.1.368 I-1 IIc-5 IId-1 M.Z.1.369 I-1 IIc-5 IId-2 M.Z.1.370 I-1IIc-5 IId-3 M.Z.1.371 I-1 IIc-6 IId-1 M.Z.1.372 I-1 IIc-6 IId-2M.Z.1.373 I-1 IIc-6 IId-3 M.Z.1.374 I-1 IIc-7 IId-1 M.Z.1.375 I-1 IIc-7IId-2 M.Z.1.376 I-1 IIc-7 IId-3 M.Z.1.377 I-1 IIc-8 IId-1 M.Z.1.378 I-1IIc-8 IId-2 M.Z.1.379 I-1 IIc-8 IId-3 M.Z.1.380 I-1 IIc-1 IIe-1M.Z.1.381 I-1 IIc-1 IIe-2 M.Z.1.382 I-1 IIc-1 IIe-3 M.Z.1.383 I-1 IIc-2IIe-1 M.Z.1.384 I-1 IIc-2 IIe-2 M.Z.1.385 I-1 IIc-2 IIe-3 M.Z.1.386 I-1IIc-3 IIe-1 M.Z.1.387 I-1 IIc-3 IIe-2 M.Z.1.388 I-1 IIc-3 IIe-3M.Z.1.389 I-1 IIc-4 IIe-1 M.Z.1.390 I-1 IIc-4 IIe-2 M.Z.1.391 I-1 IIc-4IIe-3 M.Z.1.392 I-1 IIc-5 IIe-1 M.Z.1.393 I-1 IIc-5 IIe-2 M.Z.1.394 I-1IIc-5 IIe-3 M.Z.1.395 I-1 IIc-6 IIe-1 M.Z.1.396 I-1 IIc-6 IIe-2M.Z.1.397 I-1 IIc-6 IIe-3 M.Z.1.398 I-1 IIc-7 IIe-1 M.Z.1.399 I-1 IIc-7IIe-2 M.Z.1.400 I-1 IIc-7 IIe-3 M.Z.1.401 I-1 IIc-8 IIe-1 M.Z.1.402 I-1IIc-8 IIe-2 M.Z.1.403 I-1 IIc-8 IIe-3 M.Z.1.404 I-1 IIc-1 IIf-1M.Z.1.405 I-1 IIc-1 IIf-2 M.Z.1.406 I-1 IIc-1 IIf-3 M.Z.1.407 I-1 IIc-2IIf-1 M.Z.1.408 I-1 IIc-2 IIf-2 M.Z.1.409 I-1 IIc-2 IIf-3 M.Z.1.410 I-1IIc-3 IIf-1 M.Z.1.411 I-1 IIc-3 IIf-2 M.Z.1.412 I-1 IIc-3 IIf-3M.Z.1.413 I-1 IIc-4 IIf-1 M.Z.1.414 I-1 IIc-4 IIf-2 M.Z.1.415 I-1 IIc-4IIf-3 M.Z.1.416 I-1 IIc-5 IIf-1 M.Z.1.417 I-1 IIc-5 IIf-2 M.Z.1.418 I-1IIc-5 IIf-3 M.Z.1.419 I-1 IIc-6 IIf-1 M.Z.1.420 I-1 IIc-6 IIf-2M.Z.1.421 I-1 IIc-6 IIf-3 M.Z.1.422 I-1 IIc-7 IIf-1 M.Z.1.423 I-1 IIc-7IIf-2 M.Z.1.424 I-1 IIc-7 IIf-3 M.Z.1.425 I-1 IIc-8 IIf-1 M.Z.1.426 I-1IIc-8 IIf-2 M.Z.1.427 I-1 IIc-8 IIf-3 M.Z.1.428 I-1 IId-1 IIe-1M.Z.1.429 I-1 IId-1 IIe-2 M.Z.1.430 I-1 IId-1 IIe-3 M.Z.1.431 I-1 IId-2IIe-1 M.Z.1.432 I-1 IId-2 IIe-2 M.Z.1.433 I-1 IId-2 IIe-3 M.Z.1.434 I-1IId-3 IIe-1 M.Z.1.435 I-1 IId-3 IIe-2 M.Z.1.436 I-1 IId-3 IIe-3M.Z.1.437 I-1 IId-1 IIf-1 M.Z.1.438 I-1 IId-1 IIf-2 M.Z.1.439 I-1 IId-1IIf-3 M.Z.1.440 I-1 IId-2 IIf-1 M.Z.1.441 I-1 IId-2 IIf-2 M.Z.1.442 I-1IId-2 IIf-3 M.Z.1.443 I-1 IId-3 IIf-1 M.Z.1.444 I-1 IId-3 IIf-2M.Z.1.445 I-1 IId-3 IIf-3 M.Z.1.446 I-1 IIe-1 IIf-1 M.Z.1.447 I-1 IIe-1IIf-2 M.Z.1.448 I-1 IIe-1 IIf-3 M.Z.1.449 I-1 IIe-2 IIf-1 M.Z.1.450 I-1IIe-2 IIf-2 M.Z.1.451 I-1 IIe-2 IIf-3 M.Z.1.452 I-1 IIe-3 IIf-1M.Z.1.453 I-1 IIe-3 IIf-2 M.Z.1.454 I-1 IIe-3 IIf-3 M.Z.1.455 I-1 IIc-6IIc-2 M.Z.1.456 I-1 IIc-6 IIc-5 M.Z.1.457 I-1 IIa-1 IIb-7 M.Z.1.458 I-1IIa-1 IIb-8 M.Z.1.459 I-1 IIa-1 IIb-9 M.Z.1.460 I-1 IIa-1 IIb-10

Table Z2

Table Z2 is as Table Z1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Z.2.1 to M.Z.2.456. Inthe context of the present invention, each of the rows of Table Z2corresponds to one mixture.

Table Z3

Table Z3 is as Table Z1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Z.3.1 to M.Z.3.456. Inthe context of the present invention, each of the rows of Table Z3corresponds to one mixture.

Table Z4

Table Z4A is as Table Z1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Z.4.1 to M.Z.4.456. Inthe context of the present invention, each of the rows of Table Z4corresponds to one mixture.

Table Z5

Table Z5 is as Table Z1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Z.5.1 to M.Z.5.456. Inthe context of the present invention, each of the rows of Table Z5corresponds to one mixture.

Table Z6

Table Z6 is as Table Z1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Z.6.1 to M.Z.6.456. Inthe context of the present invention, each of the rows of Table Z6corresponds to one mixture.

Table Z7

Table Z7 is as Table Z1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Z.7.1 to M.Z.7.456. Inthe context of the present invention, each of the rows of Table Z7corresponds to one mixture.

Table Z8

Table Z8 is as Table Z1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Z.8.1 to M.Z.8.456. Inthe context of the present invention, each of the rows of Table Z8corresponds to one mixture.

Table Z9

Table Z9 is as Table Z1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Z.9.1 to M.Z.9.456. Inthe context of the present invention, each of the rows of Table Z9corresponds to one mixture.

Table Z10

Table Z10 is as Table Z1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Z.10.1 to M.Z.10.456.In the context of the present invention, each of the rows of Table Z10corresponds to one mixture.

Table Z11

Table Z11 is as Table Z1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Z.11.1 to M.Z.11.456.In the context of the present invention, each of the rows of Table Z11corresponds to one mixture.

Table Z12

Table Z12 is as Table Z1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Z.12.1 to M.Z.12.456.In the context of the present invention, each of the rows of Table Z12corresponds to one mixture.

The invention also relates to the ternary mixtures comprising onecompound land two compunds 11, wherein, wherein the first compound II(compound II-1) is metrafenone and the other compound II (compound II-2)is selected from the group consisting of

(a) strobilurines such as azoxystrobin; kresoxim-methyl; mandestrobin,meta-minostrobin; picoxystrobin; pyraclostrobin or trifloxystrobin; and

(b) azoles such as cyproconazole; difenoconazole; epoxiconazole;metconazole (; pro-piconazole; prothioconazole; tebuconazole;triticonazole or bromoconazole;

(c) morphopholines such as fenpropimorph, tridemorph, fenpropidin andspiroxamine;

(d) chlorothalonil; and

(e)2-[[(7R,8R,9S)-7-benzyl-9-methyl-8-(2-methylpropanoyloxy)-2,6-dioxo-1,5-dioxonan-3-yl]carbamoyl]-4-methoxy-3-pyridyl]oxymethyl2-methylpropanoate (ii-z-01) and[[(6S,7R,8R)-8-benzyl-3-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl]2-methylpropanoate (ii-z-02).

Preferred compounds II-2 are selected from

(a) strobilurines such as azoxystrobin; kresoxim-methyl; picoxystrobin;pyraclostrobin or trifloxystrobin; and

(b) azoles such as propiconazole, prothioconazole or bromoconazoke;

(c) morphopholines such as fenpropimorph, fenpropidin and spiroxamine;

(d) chlorothalonil; and

(e)2-[[(7R,8R,9S)-7-benzyl-9-methyl-8-(2-methylpropanoyloxy)-2,6-dioxo-1,5-dioxonan-3-yl]carbamoyl]-4-methoxy-3-pyridylloxymethyl2-methylpropanoate and[(6S,7R,8R)-8-benzyl-3-[(3-hydroxy-4-methoxy-pyridine-2-carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl]2-methylpropanoate; and

(f) SDHIs such as benzovindiflupyr, bixafen, boscalid, fluopyram andfluxapyroxad

More preferred second compounds II are selected from pyraclostrobin,propiconazole, prothioconazole and chlorothalonil.

These ternary mixtures are shown below in Tables Za1 to Za12.

TABLE Za1 No I II-1 II-2 M.Za.1.1 I-1 metrafenone pyraclostrobinM.Za.1.2 I-1 metrafenone propiconazole M.Za.1.3 I-1 metrafenoneprothioconazole M.Za.1.4 I-1 metrafenone chlorothalonil M.Za.1.5 I-1metrafenone azoxystrobin M.Za.1.6 I-1 metrafenone kresoxim-methylM.Za.1.7 I-1 metrafenone picoxystrobin M.Za.1.8 I-1 metrafenonetrifloxystrobin M.Za.1.9 I-1 metrafenone bromoconazole M.Za.1.10 I-1metrafenone fenpropimorph M.Za.1.11 I-1 metrafenone fenpropidinM.Za.1.12 I-1 metrafenone spiroxamine M.Za.1.13 I-1 metrafenone II-z-01M.Za.1.14 I-1 metrafenone II-z-02 M.Za.1.15 I-1 metrafenone mandestrobinM.Za.1.16 I-1 metrafenone metaminostrobin M.Za.1.17 I-1 metrafenonetebuconazole M.Za.1.18 I-1 metrafenone triticonazole M.Za.1.19 I-1metrafenone cyproconazole M.Za.1.20 I-1 metrafenone difenoconazoleM.Za.1.21 I-1 metrafenone epoxiconazole M.Za.1.22 I-1 metrafenonemetconazole M.Za.1.23 I-1 metrafenone tridemorph M.Za.1.24 I-1metrafenone benzovindiflupyr M.Za.1.25 I-1 metrafenone bixafen M.Za.1.26I-1 metrafenone boscalid M.Za.1.27 I-1 metrafenone fluopyram M.Za.1.28I-1 metrafenone fluxapyroxad

Table Za2

Table Za2 is as Table Za1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Za.2.1 to M.Za.2.28. Inthe context of the present invention, each of the rows of Table Za2corresponds to one mixture.

Table Za3

Table Za3 is as Table Za1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Za.3.1 to M.Za.3.28. Inthe context of the present invention, each of the rows of Table Za3corresponds to one mixture.

Table Za4

Table Za4A is as Table Za1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Za.4.1 to M.Za.4.28. Inthe context of the present invention, each of the rows of Table Za4corresponds to one mixture.

Table Za5

Table Za5 is as Table Za1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Za.5.1 to M.Za.5.28. Inthe context of the present invention, each of the rows of Table Za5corresponds to one mixture.

Table Za6

Table Za6 is as Table Za1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Za.6.1 to M.Za.6.28. Inthe context of the present invention, each of the rows of Table Za6corresponds to one mixture.

Table Za7

Table Za7 is as Table Za1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Za.7.1 to M.Za.7.28. Inthe context of the present invention, each of the rows of Table Za7corresponds to one mixture.

Table Za8

Table Za8 is as Table Za1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Za.8.1 to M.Za.8.28. Inthe context of the present invention, each of the rows of Table Za8corresponds to one mixture.

Table Za9

Table Za9 is as Table Za1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Za.9.1 to M.Za.9.28. Inthe context of the present invention, each of the rows of Table Za9corresponds to one mixture.

Table Za10

Table Za10 is as Table Za1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Za.10.1 to M.Za.10.28.In the context of the present invention, each of the rows of Table Za10corresponds to one mixture.

Table Za11

Table Za11 is as Table Za1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Za.11.1 to M.Za.11.28.In the context of the present invention, each of the rows of Table Za11corresponds to one mixture.

Table Za12

Table Za12 is as Table Za1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Za.12.1 to M.Za.12.28.In the context of the present invention, each of the rows of Table Za12corresponds to one mixture.

Within tables Za1 to Za12, the following mixtures are preferred:

M.Za.1.1, M.Za.1.2, M.Za.1.3, M.Za.1.4, M.Za.1.5, M.Za.1.6, M.Za.1.7,M.Za.1.8, M.Za.1.9, M.Za.1.10, M.Za.1.11, M.Za.1.12, M.Za.1.28

M.Za.2.1, M.Za.2.2, M.Za.2.3, M.Za.2.4, M.Za.2.5, M.Za.2.6, M.Za.2.7,M.Za.2.8, M.Za.2.9, M.Za.2.10, M.Za.2.11, M.Za.2.12, M.Za.2.28

M.Za.3.1, M.Za.3.2, M.Za.3.3, M.Za.3.4, M.Za.3.5, M.Za.3.6, M.Za.3.7,M.Za.3.8, M.Za.3.9, M.Za.3.10, M.Za.3.11, M.Za.3.12, M.Za.3.28

M.Za.4.1, M.Za.4.2, M.Za.4.3, M.Za.4.4, M.Za.4.5, M.Za.4.6, M.Za.4.7,M.Za.4.8, M.Za.4.9, M.Za.4.10, M.Za.4.11, M.Za.4.12, M.Za.4.28

M.Za.5.1, M.Za.5.2, M.Za.5.3, M.Za.5.4, M.Za.5.5, M.Za.5.6, M.Za.5.7,M.Za.5.8, M.Za.5.9, M.Za.5.10, M.Za.5.11, M.Za.5.12, M.Za.5.28

M.Za.6.1, M.Za.6.2, M.Za.6.3, M.Za.6.4, M.Za.6.5, M.Za.6.6, M.Za.6.7,M.Za.6.8, M.Za.6.9, M.Za.6.10, M.Za.6.11, M.Za.6.12, M.Za.6.28

M.Za.7.1, M.Za.7.2, M.Za.7.3, M.Za.7.4, M.Za.7.5, M.Za.7.6, M.Za.7.7,M.Za.7.8, M.Za.7.9, M.Za.7.10, M.Za.7.11, M.Za.7.12, M.Za.7.28

M.Za.8.1, M.Za.8.2, M.Za.8.3, M.Za.8.4, M.Za.8.5, M.Za.8.6, M.Za.8.7,M.Za.8.8, M.Za.8.9, M.Za.8.10, M.Za.8.11, M.Za.8.12, M.Za.8.28

.Za.9.1, M.Za.9.2, M.Za.9.3, M.Za.9.4, M.Za.9.5, M.Za.9.6, M.Za.9.7,M.Za.9.8, M.Za.9.9, M.Za.9.10, M.Za.9.11, M.Za.9.12, M.Za.9.28

M.Za.10.1, M.Za.10.2, M.Za.10.3, M.Za.10.4, M.Za.10.5, M.Za.10.6,M.Za.10.7, M.Za.10.8, M.Za.10.9, M.Za.10.10, M.Za.10.11, M.Za.10.12,M.Za.10.28

M.Za.11.1, M.Za.11.2, M.Za.11.3, M.Za.11.4, M.Za.11.5, M.Za.11.6,M.Za.11.7, M.Za.11.8, M.Za.11.9, M.Za.11.10, M.Za.11.11, M.Za.11.12,M.Za.11.28

M.Za.12.1, M.Za.12.2, M.Za.12.3, M.Za.12.4, M.Za.12.5, M.Za.12.6,M.Za.12.7, M.Za.12.8, M.Za.12.9, M.Za.12.10, M.Za.12.11, M.Za.12.12 andM.Za.12.28.

Within tables Za1 to Za12, the following mixtures are more preferred:

M.Za.1.1, M.Za.1.2, M.Za.1.3, M.Za.1.4, M.Za.1.28,

M.Za.2.1, M.Za.2.2, M.Za.2.3, M.Za.2.4, M.Za.2.28,

M.Za.3.1, M.Za.3.2, M.Za.3.3, M.Za.3.4, M.Za.3.28,

M.Za.4.1, M.Za.4.2, M.Za.4.3, M.Za.4.4, M.Za.4.28,

M.Za.5.1, M.Za.5.2, M.Za.5.3, M.Za.5.4 M.Za.5.28,

M.Za.6.1, M.Za.6.2, M.Za.6.3, M.Za.6.4, M.Za.6.28,

M.Za.7.1, M.Za.7.2, M.Za.7.3, M.Za.7.4, M.Za.7.28,

M.Za.8.1, M.Za.8.2, M.Za.8.3, M.Za.8.4, M.Za.8.28,

M.Za.9.1, M.Za.9.2, M.Za.9.3, M.Za.9.4, M.Za.9.28,

M.Za.10.1, M.Za.10.2, M.Za.10.3, M.Za.10.4, M.Za.10.28,

M.Za.11.1, M.Za.11.2, M.Za.11.3, M.Za.11.4, M.Za.11.28,

M.Za.12.1, M.Za.12.2, M.Za.12.3, M.Za.12.4 and M.Za.12.28.

The invention also relates to the ternary mixtures comprising onecompound land two compunds II, wherein the first compound II (compoundII-1) is propiconazole and the other compound II (compound II-2) isselected from the group consisting of

(a) strobilurines such as azoxystrobin; kresoxim-methyl; mandestrobin,metaminostrobin; picoxystrobin; pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, tridemorph, fenpropidin andspiroxamine; and

(d) chlorothalonil.

Preferred compounds II-2 are selected from

(a) strobilurines such as azoxystrobin; kresoxim-methyl; picoxystrobin;pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, fenpropidin and spiroxamine;and

(d) chlorothalonil.

Most preferred second compounds II are selected from pyraclostrobinchlorothalonil.

These ternary mixtures are shown below in Tables Zb1 to Zb12 as hereinset forth below.

TABLE Zb1 No I 11 (1) II (2) M.Zb.1.1 I-1 propicona-zole pyraclostrobinM.Zb.1.2 I-1 propicona-zole chlorothalonil M.Zb.1.3 I-1 propicona-zoleazoxystrobin M.Zb.1.4 I-1 propicona-zole kresoxim-methyl M.Zb.1.5 I-1propicona-zole picoxystrobin M.Zb.1.6 I-1 propicona-zole trifloxystrobinM.Zb.1.7 I-1 propicona-zole fenpropimorph M.Zb.1.8 I-1 propicona-zolefenpropidin M.Zb.1.9 I-1 propicona-zole spiroxamine M.Zb.1.10 I-1propicona-zole tridemorph M.Zb.1.11 I-1 propicona-zole mandestrobinM.Zb.1.12 I-1 propicona-zole metaminostrobin

Table Zb2

Table Zb2 is as Table Zb1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Zb.2.1 to M.Zb.2.12. Inthe context of the present invention, each of the rows of Table Zb2corresponds to one mixture.

Table Zb3

Table Zb3 is as Table Zb1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Zb.3.1 to M.Zb.3.12. Inthe context of the present invention, each of the rows of Table Zb3corresponds to one mixture.

Table Zb4

Table Zb4A is as Table Zb1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Zb.4.1 to M.Zb.4.12. Inthe context of the present invention, each of the rows of Table Zb4corresponds to one mixture.

Table Zb5

Table Zb5 is as Table Zb1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Zb.5.1 to M.Zb.5.12. Inthe context of the present invention, each of the rows of Table Zb5corresponds to one mixture.

Table Zb6

Table Zb6 is as Table Zb1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Zb.6.1 to M.Zb.6.12. Inthe context of the present invention, each of the rows of Table Zb6corresponds to one mixture.

Table Zb7

Table Zb7 is as Table Zb1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Zb.7.1 to M.Zb.7.12. Inthe context of the present invention, each of the rows of Table Zb7corresponds to one mixture.

Table Zb8

Table Zb8 is as Table Zb1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Zb.8.1 to M.Zb.8.12. Inthe context of the present invention, each of the rows of Table Zb8corresponds to one mixture.

Table Zb9

Table Zb9 is as Table Zb1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Zb.9.1 to M.Zb.9.12. Inthe context of the present invention, each of the rows of Table Zb9corresponds to one mixture.

Table Zb10

Table Zb10 is as Table Zb1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Zb.10.1 to M.Zb.10.12.In the context of the present invention, each of the rows of Table Zb10corresponds to one mixture.

Table Zb11

Table Zb11 is as Table Zb1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Zb.11.1 to M.Zb.11.12.In the context of the present invention, each of the rows of Table Zb11corresponds to one mixture.

Table Zb12

Table Zba12 is as Table Zba1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Zba.12.1 toM.Zba.12.12. In the context of the present invention, each of the rowsof Table Zba12 corresponds to one mixture.

Within tables Zb1 to Zb12, the following mixtures are preferred:

M.Zb.1.1, M.Zb.1.2, M.Zb.1.3, M.Zb.1.4, M.Zb.1.5, M.Zb.1.6, M.Zb.1.7,M.Zb.1.8, M.Zb.1.9, M.Zb.2.1, M.Zb.2.2, M.Zb.2.3, M.Zb.2.4, M.Zb.2.5,M.Zb.2.6, M.Zb.2.7, M.Zb.2.8, M.Zb.2.9, M.Zb.3.1, M.Zb.3.2, M.Zb.3.3,M.Zb.3.4, M.Zb.3.5, M.Zb.3.6, M.Zb.3.7, M.Zb.3.8, M.Zb.3.9, M.Zb.4.1,M.Zb.4.2, M.Zb.4.3, M.Zb.4.4, M.Zb.4.5, M.Zb.4.6, M.Zb.4.7, M.Zb.4.8,M.Zb.4.9, M.Zb.5.1, M.Zb.5.2, M.Zb.5.3, M.Zb.5.4, M.Zb.5.5, M.Zb.5.6,M.Zb.5.7, M.Zb.5.8, M.Zb.5.9, M.Zb.6.1, M.Zb.6.2, M.Zb.6.3, M.Zb.6.4,M.Zb.6.5, M.Zb.6.6, M.Zb.6.7, M.Zb.6.8, M.Zb.6.9, M.Zb.7.1, M.Zb.7.2,M.Zb.7.3, M.Zb.7.4, M.Zb.7.5, M.Zb.7.6, M.Zb.7.7, M.Zb.7.8, M.Zb.7.9,M.Zb.8.1, M.Zb.8.2, M.Zb.8.3, M.Zb.8.4, M.Zb.8.5, M.Zb.8.6, M.Zb.8.7,M.Zb.8.8, M.Zb.8.9, M.Zb.9.1, M.Zb.9.2, M.Zb.9.3, M.Zb.9.4, M.Zb.9.5,M.Zb.9.6, M.Zb.9.7, M.Zb.9.8, M.Zb.9.9, M.Zb.10.1, M.Zb.10.2, M.Zb.10.3,M.Zb.10.4, M.Zb.10.5, M.Zb.10.6, M.Zb.10.7, M.Zb.10.8, M.Zb.10.9,

M.Zb.11.1, M.Zb.11.2, M.Zb.11.3, M.Zb.11.4, M.Zb.11.5, M.Zb.11.6,M.Zb.11.7, M.Zb.11.8, M.Zb.11.9,

M.Zb.12.1, M.Zb.12.2, M.Zb.12.3, M.Zb.12.4, M.Zb.12.5, M.Zb.12.6,M.Zb.12.7, M.Zb.12.8 and M.Zb.12.9.

Within tables Zb1 to Zb12, the following mixtures are more preferred:

M.Zb.1.1, M.Zb.1.2 M.Zb.2.1, M.Zb.2.2 M.Zb.3.1, M.Zb.3.2 M.Zb.4.1,M.Zb.4.2 M.Zb.5.1, M.Zb.5.2 M.Zb.6.1, M.Zb.6.2 M.Zb.7.1, M.Zb.7.2M.Zb.8.1, M.Zb.8.2 M.Zb.9.1, M.Zb.9.2 M.Zb.10.1, M.Zb.10.2 M.Zb.11.1,M.Zb.11.2 M.Zb.12.1 and M.Zb.12.2.

The invention also relates to the ternary mixtures comprising onecompound land two compunds 11, wherein, wherein the first compound 11(compound II-1) is fluxapyroxad and the other compound 11 (compoundII-2) is selected from the group consisting of

(a) strobilurines such as azoxystrobin; kresoxim-methyl; mandestrobin,meta-minostrobin; picoxystrobin; pyraclostrobin or trifloxystrobin; and

(b) azoles such as cyproconazole; difenoconazole; epoxiconazole;metconazole (; pro-piconazole; prothioconazole; tebuconazole ortriticonazole;

(c) morphopholines such as fenpropimorph, tridemorph, fenpropidin andspiroxamine and

(d) chlorothalonil.

Preferred compounds II-2 are selected from

(a) strobilurines such as azoxystrobin; kresoxim-methyl; picoxystrobin;pyraclostrobin or trifloxystrobin; and

(b) azoles such as propiconazole or prothioconazole;

(c) morphopholines such as fenpropimorph, fenpropidin and spiroxamine;and

(d) chlorothalonil; and

More preferred second compounds II are selected from pyraclostrobin,propiconazole, prothioconazole and chlorothalonil.

These ternary mixtures are shown below in Tables Zc1 to Zc12.

TABLE Za1 No I II-1 II-2 M.Zc.1.1 I-1 fluxapyroxad pyraclostrobinM.Zc.1.2 I-1 fluxapyroxad propiconazole M.Zc.1.3 I-1 fluxapyroxadprothioconazole M.Zc.1.4 I-1 fluxapyroxad chlorothalonil M.Zc.1.5 I-1fluxapyroxad azoxystrobin M.Zc.1.6 I-1 fluxapyroxad kresoxim-methylM.Zc.1.7 I-1 fluxapyroxad picoxystrobin M.Zc.1.8 I-1 fluxapyroxadtrifloxystrobin M.Zc.1.9 I-1 fluxapyroxad fenpropimorph M.Zc.1.10 I-1fluxapyroxad fenpropidin M.Zc.1.11 I-1 fluxapyroxad spiroxamineM.Zc.1.12 I-1 fluxapyroxad mandestrobin M.Zc.1.13 I-1 fluxapyroxadmetaminostrobin M.Zc.1.14 I-1 fluxapyroxad tebuconazole M.Zc.1.15 I-1fluxapyroxad triticonazole M.Zc.1.16 I-1 fluxapyroxad cyproconazoleM.Zc.1.17 I-1 fluxapyroxad difenoconazole M.Zc.1.18 I-1 fluxapyroxadepoxiconazole M.Zc.1.19 I-1 fluxapyroxad metconazole M.Zc.1.20 I-1fluxapyroxad tridemorph

Table Zc2

Table Zc2 is as Table Zc1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Zc.2.1 to M.Zc.2.20. Inthe context of the present invention, each of the rows of Table Zc2corresponds to one mixture.

Table Zc3

Table Zc3 is as Table Zc1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Zc.3.1 to M.Zc.3.20. Inthe context of the present invention, each of the rows of Table Zc3corresponds to one mixture.

Table Zc4

Table Zc4A is as Table Zc1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Zc.4.1 to M.Zc.4.20. Inthe context of the present invention, each of the rows of Table Zc4corresponds to one mixture.

Table Zc5

Table Zc5 is as Table Zc1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Zc.5.1 to M.Zc.5.20. Inthe context of the present invention, each of the rows of Table Zc5corresponds to one mixture.

Table Zc6

Table Zc6 is as Table Zc1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Zc.6.1 to M.Zc.6.20. Inthe context of the present invention, each of the rows of Table Zc6corresponds to one mixture.

Table Zc7

Table Zc7 is as Table Zc1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Zc.7.1 to M.Zc.7.20. Inthe context of the present invention, each of the rows of Table Zc7corresponds to one mixture.

Table Zc8

Table Zc8 is as Table Zc1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Zc.8.1 to M.Zc.8.20. Inthe context of the present invention, each of the rows of Table Zc8corresponds to one mixture.

Table Zc9

Table Zc9 is as Table Zc1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Zc.9.1 to M.Zc.9.20. Inthe context of the present invention, each of the rows of Table Zc9corresponds to one mixture.

Table Zc10

Table Zc10 is as Table Zc1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Zc.10.1 to M.Zc.10.20.In the context of the present invention, each of the rows of Table Zc10corresponds to one mixture.

Table Zc11

Table Zc11 is as Table Zc1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Zc.11.1 to M.Zc.11.20.In the context of the present invention, each of the rows of Table Zc11corresponds to one mixture.

Table Zc12

Table Zc12 is as Table Zc1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Zc.12.1 to M.Zc.12.20.In the context of the present invention, each of the rows of Table Zc12corresponds to one mixture.

Within tables Zc1 to Zc12, the following mixtures are preferred:

M.Zc.1.1, M.Zc.1.2, M.Zc.1.3, M.Zc.1.4, M.Zc.1.5, M.Zc.1.6, M.Zc.1.7,M.Zc.1.8, M.Zc.1.9, M.Zc.1.10, M.Zc.1.11

M.Zc.2.1, M.Zc.2.2, M.Zc.2.3, M.Zc.2.4, M.Zc.2.5, M.Zc.2.6, M.Zc.2.7,M.Zc.2.8, M.Zc.2.9, M.Zc.2.10, M.Zc.2.11

M.Zc.3.1, M.Zc.3.2, M.Zc.3.3, M.Zc.3.4, M.Zc.3.5, M.Zc.3.6, M.Zc.3.7,M.Zc.3.8, M.Zc.3.9, M.Zc.3.10, M.Zc.3.11

M.Zc.4.1, M.Zc.4.2, M.Zc.4.3, M.Zc.4.4, M.Zc.4.5, M.Zc.4.6, M.Zc.4.7,M.Zc.4.8, M.Zc.4.9, M.Zc.4.10, M.Zc.4.11

M.Zc.5.1, M.Zc.5.2, M.Zc.5.3, M.Zc.5.4, M.Zc.5.5, M.Zc.5.6, M.Zc.5.7,M.Zc.5.8, M.Zc.5.9, M.Zc.5.10, M.Zc.5.11

M.Zc.6.1, M.Zc.6.2, M.Zc.6.3, M.Zc.6.4, M.Zc.6.5, M.Zc.6.6, M.Zc.6.7,M.Zc.6.8, M.Zc.6.9, M.Zc.6.10, M.Zc.6.11

M.Zc.7.1, M.Zc.7.2, M.Zc.7.3, M.Zc.7.4, M.Zc.7.5, M.Zc.7.6, M.Zc.7.7,M.Zc.7.8, M.Zc.7.9, M.Zc.7.10, M.Zc.7.11

M.Zc.8.1, M.Zc.8.2, M.Zc.8.3, M.Zc.8.4, M.Zc.8.5, M.Zc.8.6, M.Zc.8.7,M.Zc.8.8, M.Zc.8.9, M.Zc.8.10, M.Zc.8.11

M.Zc.9.1, M.Zc.9.2, M.Zc.9.3, M.Zc.9.4, M.Zc.9.5, M.Zc.9.6, M.Zc.9.7,M.Zc.9.8, M.Zc.9.9, M.Zc.9.10, M.Zc.9.11

M.Zc.10.1, M.Zc.10.2, M.Zc.10.3, M.Zc.10.4, M.Zc.10.5, M.Zc.10.6,M.Zc.10.7, M.Zc.10.8, M.Zc.10.9, M.Zc.10.10, M.Zc.10.11

M.Zc.11.1, M.Zc.11.2, M.Zc.11.3, M.Zc.11.4, M.Zc.11.5, M.Zc.11.6,M.Zc.11.7, M.Zc.11.8, M.Zc.11.9, M.Zc.11.10, M.Zc.11.11

M.Zc.12.1, M.Zc.12.2, M.Zc.12.3, M.Zc.12.4, M.Zc.12.5, M.Zc.12.6,M.Zc.12.7, M.Zc.12.8, M.Zc.12.9, M.Zc.12.10 and M.Zc.12.11.

Within tables Zc1 to Zc12, the following mixtures are more preferred:M.Zc.1.1, M.Zc.1.2, M.Zc.1.3, M.Zc.1.4,

M.Zc.2.1, M.Zc.2.2, M.Zc.2.3, M.Zc.2.4,

M.Zc.3.1, M.Zc.3.2, M.Zc.3.3, M.Zc.3.4,

M.Zc.4.1, M.Zc.4.2, M.Zc.4.3, M.Zc.4.4,

M.Zc.5.1, M.Zc.5.2, M.Zc.5.3, M.Zc.5.4,

M.Zc.6.1, M.Zc.6.2, M.Zc.6.3, M.Zc.6.4,

M.Zc.7.1, M.Zc.7.2, M.Zc.7.3, M.Zc.7.4,

M.Zc.8.1, M.Zc.8.2, M.Zc.8.3, M.Zc.8.4,

M.Zc.9.1, M.Zc.9.2, M.Zc.9.3, M.Zc.9.4,

M.Zc.10.1, M.Zc.10.2, M.Zc.10.3, M.Zc.10.4,

M.Zc.11.1, M.Zc.11.2, M.Zc.11.3, M.Zc.11.4,

M.Zc.12.1, M.Zc.12.2, M.Zc.12.3 and M.Zc.12.4.

The invention also relates to the ternary mixtures comprising onecompound I and two compounds 11, wherein the first compound II (compoundII-1) is chlorothalonil and the other compound II (compound II-2) isselected from the group consisting of

(a) strobilurines such as azoxystrobin; kresoxim-methyl; mandestrobin,meta-minostrobin; picoxystrobin; pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, tridemorph, fenpropidin andspiroxamine.

Preferred compounds II-2 are selected from

(a) strobilurines such as azoxystrobin; kresoxim-methyl; picoxystrobin;pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, fenpropidin and spiroxamine

Most preferred, the ternary mixtures comprise one compound I,chlorothalonil and pyraclostrobin.

These ternary mixtures are shown below in Tables Zd1 to Zd12 as hereinset forth below.

TABLE Zd1 No I 11 (1) II (2) M.Zd.1.1 I-1 chlorothalonil pyraclostrobinM.Zd.1.2 I-1 chlorothalonil azoxystrobin M.Zd.1.3 I-1 chlorothalonilkresoxim-methyl M.Zd.1.4 I-1 chlorothalonil picoxystrobin M.Zd.1.5 I-1chlorothalonil trifloxystrobin M.Zd.1.6 I-1 chlorothalonil fenpropimorphM.Zd.1.7 I-1 chlorothalonil fenpropidin M.Zd.1.8 I-1 chlorothalonilspiroxamine M.Zd.1.9 I-1 chlorothalonil tridemorph M.Zd.1.10 I-1chlorothalonil mandestrobin M.Zd.1.11 I-1 chlorothalonil metaminostrobin

Table Zd2

Table Zd2 is as Table Zd1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Zd.2.1 to M.Zd.2.11. Inthe context of the present invention, each of the rows of Table Zd2corresponds to one mixture.

Table Zd3

Table Zd3 is as Table Zd1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Zd.3.1 to M.Zd.3.11. Inthe context of the present invention, each of the rows of Table Zd3corresponds to one mixture.

Table Zd4

Table Zd4A is as Table Zd1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Zd.4.1 to M.Zd.4.11. Inthe context of the present invention, each of the rows of Table Zd4corresponds to one mixture.

Table Zd5

Table Zd5 is as Table Zd1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Zd.5.1 to M.Zd.5.11. Inthe context of the present invention, each of the rows of Table Zd5corresponds to one mixture.

Table Zd6

Table Zd6 is as Table Zd1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Zd.6.1 to M.Zd.6.11. Inthe context of the present invention, each of the rows of Table Zd6corresponds to one mixture.

Table Zd7

Table Zd7 is as Table Zd1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Zd.7.1 to M.Zd.7.11. Inthe context of the present invention, each of the rows of Table Zd7corresponds to one mixture.

Table Zd8

Table Zd8 is as Table Zd1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Zd.8.1 to M.Zd.8.11. Inthe context of the present invention, each of the rows of Table Zd8corresponds to one mixture.

Table Zd9

Table Zd9 is as Table Zd1, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Zd.9.1 to M.Zd.9.11. Inthe context of the present invention, each of the rows of Table Zd9corresponds to one mixture.

Table Zd10

Table Zd10 is as Table Zd1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Zd.10.1 to M.Zd.10.11.In the context of the present invention, each of the rows of Table Zd10corresponds to one mixture.

Table Zd 11

Table Zd11 is as Table Zd1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Zd.11.1 to M.Zd.11.11.In the context of the present invention, each of the rows of Table Zd11corresponds to one mixture.

Table Zd12

Table Zd12 is as Table Zd1, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Zd.12.1 to M.Zd.12.11.In the context of the present invention, each of the rows of Table Zda12corresponds to one mixture.

Within tables Zd1 to Zd12, the following mixtures are preferred:

M.Zb.1.1, M.Zb.1.2, M.Zb.1.3, M.Zb.1.4, M.Zb.1.5, M.Zb.1.6, M.Zb.1.7,M.Zb.1.8 , M.Zb.2.1, M.Zb.2.2, M.Zb.2.3, M.Zb.2.4, M.Zb.2.5, M.Zb.2.6,M.Zb.2.7, M.Zb.2.8 , M.Zb.3.1, M.Zb.3.2, M.Zb.3.3, M.Zb.3.4, M.Zb.3.5,M.Zb.3.6, M.Zb.3.7, M.Zb.3.8 , M.Zb.4.1, M.Zb.4.2, M.Zb.4.3, M.Zb.4.4,M.Zb.4.5, M.Zb.4.6, M.Zb.4.7, M.Zb.4.8 ,

M.Zb.5.1, M.Zb.5.2, M.Zb.5.3, M.Zb.5.4, M.Zb.5.5, M.Zb.5.6, M.Zb.5.7,M.Zb.5.8 , M.Zb.6.1, M.Zb.6.2, M.Zb.6.3, M.Zb.6.4, M.Zb.6.5, M.Zb.6.6,M.Zb.6.7, M.Zb.6.8 , M.Zb.7.1, M.Zb.7.2, M.Zb.7.3, M.Zb.7.4, M.Zb.7.5,M.Zb.7.6, M.Zb.7.7, M.Zb.7.8 , M.Zb.8.1, M.Zb.8.2, M.Zb.8.3, M.Zb.8.4,M.Zb.8.5, M.Zb.8.6, M.Zb.8.7, M.Zb.8.8 , M.Zb.9.1, M.Zb.9.2, M.Zb.9.3,M.Zb.9.4, M.Zb.9.5, M.Zb.9.6, M.Zb.9.7, M.Zb.9.8 ,

M.Zb.10.1, M.Zb.10.2, M.Zb.10.3, M.Zb.10.4, M.Zb.10.5, M.Zb.10.6,M.Zb.10.7, M.Zb.10.8, M.Zb.11.1, M.Zb.11.2, M.Zb.11.3, M.Zb.11.4,M.Zb.11.5, M.Zb.11.6, M.Zb.11.7, M.Zb.11.8, M.Zb.12.1, M.Zb.12.2,M.Zb.12.3, M.Zb.12.4, M.Zb.12.5, M.Zb.12.6, M.Zb.12. and M.Zb.12.8.,

Within tables Zd1 to Zd12, the following mixtures are most preferred:

M.Zb.1.1, M.Zb.2.1, M.Zb.3.1, M.Zb.4.1, M.Zb.5.1, M.Zb.6.1, M.Zb.7.1,M.Zb.8.1, M.Zb.9.1,

M.Zb.10.1, M.Zb.11.1 and M.Zb.12.1.

The invention also relates to the ternary mixtures comprising onecompound land two compounds II, wherein the first compound II (compoundII-1) is prothioconazole and the other compound II (compound II-2) isselected from the group consisting of

(a) strobilurines such as azoxystrobin; kresoxim-methyl; mandestrobin,meta-minostrobin; picoxystrobin; pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, tridemorph, fenpropidin andspiroxamine; and

(d) chlorothalonil.

Preferred compounds II-2 are selected from

(a) strobilurines such as azoxystrobin; kresoxim-methyl; picoxystrobin;pyraclostrobin or trifloxystrobin; and

(c) morphopholines such as fenpropimorph, fenpropidin and spiroxamine;and

(d) chlorothalonil.

Most preferred second compounds II are selected from pyraclostrobinchlorothalonil.

These ternary mixtures are shown below in Tables Ze1 to Ze12 as hereinset forth below.

TABLE Ze1 No I 11 (1) II (2) M.Ze.1.1 I-1 prothioconazole pyraclostrobinM.Ze.1.2 I-1 prothioconazole chlorothalonil M.Ze.1.3 I-1 prothioconazoleazoxystrobin M.Ze.1.4 I-1 prothioconazole kresoxim-methyl M.Ze.1.5 I-1prothioconazole picoxystrobin M.Ze.1.6 I-1 prothioconazoletrifloxystrobin M.Ze.1.7 I-1 prothioconazole fenpropimorph M.Ze.1.8 I-1prothioconazole fenpropidin M.Ze.1.9 I-1 prothioconazole spiroxamineM.Ze.1.10 I-1 prothioconazole tridemorph M.Ze.1.11 I-1 prothioconazolemandestrobin M.Ze.1.12 I-1 prothioconazole metaminostrobin

Table Ze2

Table Ze2 is as Table Ze1, in which the compound I-1 is replaced bycompound I-2, and the mixtures are named from M.Ze.2.1 to M.Ze.2.12. Inthe context of the present invention, each of the rows of Table Ze2corresponds to one mixture.

Table Ze3

Table Ze3 is as Table Ze1, in which the compound I-1 is replaced bycompound I-3, and the mixtures are named from M.Ze.3.1 to M.Ze.3.12. Inthe context of the present invention, each of the rows of Table Ze3corresponds to one mixture.

Table Ze4

Table Ze4A is as Table Ze1, in which the compound I-1 is replaced bycompound I-4, and the mixtures are named from M.Ze.4.1 to M.Ze.4.12. Inthe context of the present invention, each of the rows of Table Ze4corresponds to one mixture.

Table Ze5

Table Ze5 is as Table Ze1, in which the compound I-1 is replaced bycompound I-5, and the mixtures are named from M.Ze.5.1 to M.Ze.5.12. Inthe context of the present invention, each of the rows of Table Ze5corresponds to one mixture.

Table Ze6

Table Ze6 is as Table Ze1, in which the compound I-1 is replaced bycompound I-6, and the mixtures are named from M.Ze.6.1 to M.Ze.6.12. Inthe context of the present invention, each of the rows of Table Ze6corresponds to one mixture.

Table Ze7

Table Ze7 is as Table Ze1, in which the compound I-1 is replaced bycompound I-7, and the mixtures are named from M.Ze.7.1 to M.Ze.7.12. Inthe context of the present invention, each of the rows of Table Ze7corresponds to one mixture.

Table Ze8

Table Ze8 is as Table Ze1, in which the compound I-1 is replaced bycompound I-8, and the mixtures are named from M.Ze.8.1 to M.Ze.8.12. Inthe context of the present invention, each of the rows of Table Ze8corresponds to one mixture.

Table Ze9

Table Ze9 is as Table Zel, in which the compound I-1 is replaced bycompound I-9, and the mixtures are named from M.Ze.9.1 to M.Ze.9.12. Inthe context of the present invention, each of the rows of Table Ze9corresponds to one mixture.

Table Ze10

Table Ze10 is as Table Ze1, in which the compound I-1 is replaced bycompound I-10, and the mixtures are named from M.Ze.10.1 to M.Ze.10.12.In the context of the present invention, each of the rows of Table Ze10corresponds to one mixture.

Table Ze11

Table Ze11 is as Table Ze1, in which the compound I-1 is replaced bycompound I-11, and the mixtures are named from M.Ze.11.1 to M.Ze.11.12.In the context of the present invention, each of the rows of Table Ze11corresponds to one mixture.

Table Ze12

Table Zea12 is as Table Zeal, in which the compound I-1 is replaced bycompound I-12, and the mixtures are named from M.Zea.12.1 toM.Zea.12.12. In the context of the pre-sent invention, each of the rowsof Table Zea12 corresponds to one mixture.

Within tables Zel to Ze12, the following mixtures are preferred:

M.Ze.1.1, M.Ze.1.2, M.Ze.1.3, M.Ze.1.4, M.Ze.1.5, M.Ze.1.6, M.Ze.1.7,M.Ze.1.8, M.Ze.1.9, M.Ze.2.1, M.Ze.2.2, M.Ze.2.3, M.Ze.2.4, M.Ze.2.5,M.Ze.2.6, M.Ze.2.7, M.Ze.2.8, M.Ze.2.9, M.Ze.3.1, M.Ze.3.2, M.Ze.3.3,M.Ze.3.4, M.Ze.3.5, M.Ze.3.6, M.Ze.3.7, M.Ze.3.8, M.Ze.3.9, M.Ze.4.1,M.Ze.4.2, M.Ze.4.3, M.Ze.4.4, M.Ze.4.5, M.Ze.4.6, M.Ze.4.7, M.Ze.4.8,M.Ze.4.9, M.Ze.5.1, M.Ze.5.2, M.Ze.5.3, M.Ze.5.4, M.Ze.5.5, M.Ze.5.6,M.Ze.5.7, M.Ze.5.8, M.Ze.5.9, M.Ze.6.1, M.Ze.6.2, M.Ze.6.3, M.Ze.6.4,M.Ze.6.5, M.Ze.6.6, M.Ze.6.7, M.Ze.6.8, M.Ze.6.9, M.Ze.7.1, M.Ze.7.2,M.Ze.7.3, M.Ze.7.4, M.Ze.7.5, M.Ze.7.6, M.Ze.7.7, M.Ze.7.8, M.Ze.7.9,M.Ze.8.1, M.Ze.8.2, M.Ze.8.3, M.Ze.8.4, M.Ze.8.5, M.Ze.8.6, M.Ze.8.7,M.Ze.8.8, M.Ze.8.9, M.Ze.9.1, M.Ze.9.2, M.Ze.9.3, M.Ze.9.4, M.Ze.9.5,M.Ze.9.6, M.Ze.9.7, M.Ze.9.8, M.Ze.9.9, M.Ze.10.1, M.Ze.10.2, M.Ze.10.3,M.Ze.10.4, M.Ze.10.5, M.Ze.10.6, M.Ze.10.7, M.Ze.10.8, M.Ze.10.9,

M.Ze.11.1, M.Ze.11.2, M.Ze.11.3, M.Ze.11.4, M.Ze.11.5, M.Ze.11.6,M.Ze.11.7, M.Ze.11.8, M.Ze.11.9,

M.Ze.12.1, M.Ze.12.2, M.Ze.12.3, M.Ze.12.4, M.Ze.12.5, M.Ze.12.6,M.Ze.12.7, M.Ze.12.8 and M.Ze.12.9.

Within tables Zel to Ze12, the following mixtures are more preferred:

M.Ze.1.1, M.Ze.1.2 M.Ze.2.1, M.Ze.2.2 M.Ze.3.1, M.Ze.3.2 M.Ze.4.1,M.Ze.4.2 M.Ze.5.1,

M.Ze.5.2 M.Ze.6.1, M.Ze.6.2 M.Ze.7.1, M.Ze.7.2 M.Ze.8.1, M.Ze.8.2M.Ze.9.1, M.Ze.9.2 M.Ze.10.1, M.Ze.10.2 M.Ze.11.1, M.Ze.11.2 M.Ze.12.1and M.Ze.12.2.

All above-referred mixtures are herein below referred to as “inventivemixtures”.

The inventive mixtures can further contain one or more insecticides,fungicides, herbicides.

The inventive mixtures can be converted into customary types ofagrochemical compositions, e. g. solutions, emulsions, suspensions,dusts, powders, pastes, granules, pressings, capsules, and mixturesthereof. Examples for composition types are suspensions (e.g. SC, OD,FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES,ME), capsules (e.g. CS, ZC), pastes, pastilles, wetTable Apowders ordusts (e.g. WP, SP,

WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g. WG, SG, GR, FG,GG, MG), insecticidal articles (e.g. LN), as well as gel formulationsfor the treatment of plant propagation materials such as seeds (e.g.GF). These and further compositions types are defined in the “Catalogueof pesticide formulation types and international coding system”,Tech-nical Monograph No. 2, 6th Ed. May 2008, CropLife International.

The compositions are prepared in a known manner, such as described byMollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001;or Knowles, New developments in crop protection product formulation,Agrow Reports DS243, T&F Informa, London, 2005.

Suitable auxiliaries are solvents, liquid carriers, solid carriers orfillers, surfactants, dispersants, emulsifiers, wetters, adjuvants,solubilizers, penetration enhancers, protective colloids, adhesionagents, thickeners, humectants, repellents, attractants, feedingstimulants, compatibilizers, bactericides, anti-freezing agents,anti-foaming agents, colorants, tackifiers and binders.

Suitable solvents and liquid carriers are water and organic solvents,such as mineral oil fractions of medium to high boiling point, e.g.kerosene, diesel oil; oils of vegeTable Aor animal origin; aliphatic,cyclic and aromatic hydrocarbons, e. g. toluene, paraffin,tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol,propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones,e.g. cyclohexanone; esters, e.g. lactates, carbonates, fatty acidesters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides,e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixturesthereof.

Suitable solid carriers or fillers are mineral earths, e.g. silicates,silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite,diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate,magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers,e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas;products of vegeTable Aorigin, e.g. cereal meal, tree bark meal, woodmeal, nutshell meal, and mixtures thereof.

Suitable surfactants are surface-active compounds, such as anionic,cationic, nonionic and amphoteric surfactants, block polymers,polyelectrolytes, and mixtures thereof. Such surfactants can be used asemusifier, dispersant, solubilizer, wetter, penetration enhancer,protective colloid, or adjuvant. Examples of surfactants are listed inMcCutcheon's, Vol.1: Emulsifiers & Detergents, McCutcheon's Directories,Glen Rock, USA, 2008 (International Ed. or North American Ed.).

Suitable anionic surfactants are alkali, alkaline earth or ammoniumsalts of sulfonates, sulfates, phosphates, carboxylates, and mixturesthereof. Examples of sulfonates are alkylarylsulfonates,diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates,sulfonates of fatty acids and oils, sulfonates of ethoxylatedalkylphenols, sulfonates of alkoxylated arylphenols, sulfonates ofcondensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes,sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates orsulfosuccinamates. Examples of sulfates are sulfates of fatty acids andoils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols,or of fatty acid esters. Examples of phosphates are phosphate esters.Examples of carboxylates are alkyl carboxylates, and carboxylatedalcohol or alkylphenol ethoxylates.

Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acidamides, amine oxides, esters, sugar-based surfactants, polymericsurfactants, and mixtures thereof. Examples of alkoxylates are compoundssuch as alcohols, alkylphenols, amines, amides, arylphenols, fatty acidsor fatty acid esters which have been alkoxylated with 1 to 50equivalents. Ethylene oxide and/or propylene oxide may be employed forthe alkoxylation, preferably ethylene oxide. Examples of N-subsitituedfatty acid amides are fatty acid glucamides or fatty acid alkanolamides.Examples of esters are fatty acid esters, glycerol esters ormonoglycerides. Examples of sugar-based surfactants are sorbitans,ethoxylated sorbitans, sucrose and glucose esters oralkylpolyglucosides. Examples of polymeric surfactants are home- orcopolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.

SuitableSuitable cationic surfactants are quaternary surfactants, forexample quaternary ammonium compounds with one or two hydrophobicgroups, or salts of long-chain primary amines. Suitable amphotericsurfactants are alkylbetains and imidazolines. Suitable block polymersare block polymers of the A-B or A-B-A type comprising blocks ofpolyethylene oxide and polypropylene oxide, or of the A-B-C typecomprising alkanol, polyethylene oxide and polypropylene oxide. Suitablepolyelectrolytes are polyacids or polybases. Examples of polyacids arealkali salts of polyacrylic acid or polyacid comb polymers. Examples ofpolybases are polyvinylamines or polyethyleneamines.

Suitable adjuvants are compounds, which have a neglecTable Aor even nopesticidal activity themselves, and which improve the biologicalperformance of the inventive mixtures on the target. Examples aresurfactants, mineral or vegeTable Aoils, and other auxilaries. Furtherexamples are listed by Knowles, Adjuvants and additives, Agrow ReportsDS256, T&F Informa UK, 2006, chapter 5.

Suitable thickeners are polysaccharides (e.g. xanthan gum,carboxymethylcellulose), anorganic clays (organically modified orunmodified), polycarboxylates, and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives suchas alkylisothiazolinones and benzisothiazolinones.

Suitable anti-freezing agents are ethylene glycol, propylene glycol,urea and glycerin.

Suitable anti-foaming agents are silicones, long chain alcohols, andsalts of fatty acids.

Suitable colorants (e.g. in red, blue, or green) are pigments of lowwater solubility and water-soluble dyes. Examples are inorganiccolorants (e.g. iron oxide, titan oxide, iron hexacyanoferrate) andorganic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).

Suitable tackifiers or binders are polyvinylpyrrolidons,polyvinylacetates, polyvinyl alcohols, polyacrylates, biological orsynthetic waxes, and cellulose ethers.

Examples for composition types and their preparation are:

i) Water-soluble concentrates (SL, LS)

10-60 wt % of an inventive mixture and 5-15 wt % wetting agent (e.g.alcohol alkoxylates) are dissolved in water and/or in a water-solublesolvent (e.g. alcohols) ad 100 wt %. The active substance dissolves upondilution with water.

ii) Dispersible concentrates (DC)

5-25 wt % of an inventive mixture and 1-10 wt % dispersant (e. g.polyvinylpyrrolidone) are dissolved in organic solvent (e.g.cyclohexanone) ad 100 wt %. Dilution with water gives a dispersion.

iii) Emulsifiable concentrates (EC)

15-70 wt % of an inventive mixture and 5-10 wt % emulsifiers (e.g.calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolvedin water-insoluble organic solvent (e.g. aromatic hydrocarbon) ad 100 wt%. Dilution with water gives an emulsion.

iv) Emulsions (EW, EO, ES)

5-40 wt % of an inventive mixture and I-10 wt % emulsifiers (e.g.calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolvedin 20-40 wt % water-insoluble organic solvent (e.g. aromatichydrocarbon). This mixture is introduced into water ad 100 wt % by meansof an emulsifying machine and made into a homogeneous emulsion. Dilutionwith water gives an emulsion.

v) Suspensions (SC, OD, FS)

In an agitated ball mill, 20-60 wt % of an inventive mixture arecomminuted with addition of 2-10 wt % dispersants and wetting agents(e.g. sodium lignosulfonate and alcohol ethoxylate), 0.1-2 wt %thickener (e.g. xanthan gum) and water ad 100 wt % to give a fine activesubstance suspension. Dilution with water gives a sTable Asuspension ofthe active substance. For FS type composition up to 40 wt % binder (e.g.polyvinylalcohol) is added.

vi) Water-dispersible granules and water-soluble granules (WG, SG)

50-80 wt % of an inventive mixture are ground finely with addition ofdispersants and wetting agents (e.g. sodium lignosulfonate and alcoholethoxylate) ad 100 wt % and prepared as water-dispersible orwater-soluble granules by means of technical appliances (e. g.extrusion, spray tower, fluidized bed). Dilution with water gives asTable Adispersion or solution of the active substance.

vii) Water-dispersible powders and water-soluble powders (WP, SP, WS)

50-80 wt % of an inventive mixture are ground in a rotor-stator millwith addition of I-5 wt % dispersants (e.g. sodium lignosulfonate), I-3wt % wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g.silica gel) ad 100 wt %. Dilution with water gives a sTable Adispersionor solution of the active substance.

viii) Gel (GW, GF)

In an agitated ball mill, 5-25 wt % of an inventive mixture arecomminuted with addition of 3-10 wt % dispersants (e.g. sodiumlignosulfonate), I-5 wt % thickener (e.g. carboxymethylcellulose) andwater ad 100 wt % to give a fine suspension of the active substance.Dilution with water gives a sTable Asuspension of the active substance.

iv) Microemulsion (ME)

5-20 wt % of an inventive mixture are added to 5-30 wt % organic solventblend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt %surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate),and water ad 100%. This mixture is stirred for 1 h to producespontaneously a thermodynamically sTable Amicroemulsion.

iv) Microcapsules (CS)

An oil phase comprising 5-50 wt % of an inventive mixture, 0-40 wt %water insoluble or-ganic solvent (e.g. aromatic hydrocarbon), 2-15 wt %acrylic monomers (e.g. methyl-methacrylate, methacrylic acid and a di-or triacrylate) are dispersed into an aqueous solution of a protectivecolloid (e.g. polyvinyl alcohol). Radical polymerization initiated by aradical initiator results in the formation of poly(meth)acrylatemicrocapsules. Alternatively, an oil phase comprising 5-50 wt % of aninventive mixture according to the invention, 0-40 wt % water insolubleorganic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer(e.g. diphenylmethene-4,4′-diisocyanatae) are dispersed into an aqueoussolution of a protective colloid (e.g. polyvinyl alcohol). The additionof a polyamine (e.g. hexamethylenediamine) results in the formation ofpolyurea microcapsules. The monomers amount to 1-10 wt %. The wt %relate to the total CS composition.

ix) Dustable powders (DP, DS)

1-10 wt % of an inventive mixture are ground finely and mixed intimatelywith solid carrier (e.g. finely divided kaolin) ad 100 wt %.

x) Granules (GR, FG)

0.5-30 wt % of an inventive mixture is ground finely and associated withsolid carrier (e.g. silicate) ad 100 wt %. Granulation is achieved byextrusion, spray-drying or fluidized bed.

xi) Ultra-low volume liquids (UL)

1-50 wt % of an inventive mixture are dissolved in organic solvent (e.g.aromatic hydrocarbon) ad 100 wt %.

The compositions types i) to xi) may optionally comprise furtherauxiliaries, such as 0.1-1 wt % bactericides, 5-15 wt % anti-freezingagents, 0.1-1 wt % anti-foaming agents, and 0.1-1 wt % colorants.

The resulting agrochemical compositions generally comprise between 0.01and 95%, preferably between 0.1 and 90%, and in particular between 0.5and 75%, by weight of active substance. The active substances areemployed in a purity of from 90% to 100%, preferably from 95% to 100%(according to NMR spectrum).

Solutions for seed treatment (LS), Suspoemulsions (SE), flowableconcentrates (FS), powders for dry treatment (DS), water-dispersiblepowders for slurry treatment (WS), water-soluble powders (SS), emulsions(ES), emulsifiable concentrates (EC) and gels (GF) are usually employedfor the purposes of treatment of plant propagation materials,particularly seeds. The compositions in question give, aftertwo-to-tenfold dilution, active substance concentrations of from 0.01 to60% by weight, preferably from 0.1 to 40%, in the ready-to-usepreparations. Application can be carried out before or during sowing.Methods for applying the inventive mixtures and compositions thereof,respectively, on to plant propagation material, especially seeds includedressing, coating, pelleting, dusting, soaking and in-furrow applicationmethods of the propagation material. Preferably, the inventive mixturesor the compositions thereof, respectively, are applied on to the plantpropagation material by a method such that germination is not induced,e. g. by seed dressing, pelleting, coating and dusting.

When employed in plant protection, the amounts of active substancesapplied are, depending on the kind of effect desired, from 0.001 to 2 kgper ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.01to 1.0 kg per ha, and in particular from 0.05 to 0.75 kg per ha.

In treatment of plant propagation materials such as seeds, e. g. bydusting, coating or drenching seed, amounts of active substance of from0.01-10kg, preferably from 0.1-1000 g, more preferably from I-100 g per100 kilogram of plant propagation material (preferably seeds) aregenerally required.

When used in the protection of materials or stored products, the amountof active substance applied depends on the kind of application area andon the desired effect. Amounts customarily applied in the protection ofmaterials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of activesubstance per cubic meter of treated material.

Various types of oils, wetters, adjuvants, fertilizer, ormicronutrients, and further pesticides (e.g. herbicides, insecticides,fungicides, growth regulators, safeners) may be added to the activesubstances or the compositions comprising them as premix or, ifappropriate not until immediately prior to use (tank mix). These agentscan be admixed with the compositions according to the invention in aweight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.

The user applies the composition according to the invention usually froma predosage device, a knapsack sprayer, a spray tank, a spray plane, oran irrigation systeM.A. Usually, the agrochemical composition is made upwith water, buffer, and/or further auxiliaries to the desiredapplication concentration and the ready-to-use spray liquor or theagrochemical composition according to the invention is thus obtained.Usually, 20 to 2000 liters, preferably 50 to 400 liters, of theready-to-use spray liquor are applied per hectare of agricultural usefularea.

According to one embodiment, individual components of the compositionaccording to the invention such as parts of a kit or parts of a binaryor ternary mixture may be mixed by the user himself in a spray tank orany other kind of vessel used for applications (e. g. seed treaterdrums, seed pelleting machinery, knapsack sprayer) and furtherauxiliaries may be added, if appropriate.

Consequently, one embodiment of the invention is a kit for preparing ausable pesticidal composition, the kit comprising a) a compositioncomprising component 1) as defined herein and at least one auxiliary;and b) a composition comprising component 2) as defined herein and atleast one auxiliary; and optionally c) a composition comprising at leastone auxiliary and optionally a further active component 3) as definedherein. As said above, the present invention comprises a method forcontrolling harmful fungi, wherein the pest, their habitat, breedinggrounds, their locus or the plants to be protected against pest attack,the soil or plant propagation material (preferably seed) are treatedwith an pesticidally effective amount of a inventive mixture.Advantageously, the inventive mixtures are suitable for controlling thefollowing fungal plant diseases:

Albugo spp. (white rust) on ornamentals, vegetables (e. g. A. candida)and sunflowers (e. g. A. tragopogonis); Alternaria spp. (Alternaria leafspot) on vegetables, rape (A. brassicola or brassicae), sugar beets (A.tenuis), fruits, rice, soybeans, potatoes (e. g. A. solani or A.alternata), tomatoes (e. g. A. solani or A. alternata) and wheat;Aphanomyces spp. on sugar beets and vegetables; Ascochyta spp. oncereals and vegetables, e. g. A. tritici (anthracnose) on wheat and A.hordei on barley; Bipolaris and Drechslera spp. (teleomorph:Cochliobolus spp.), e. g. Southern leaf blight (D. maydis) or Northernleaf blight (B. zeicola) on corn, e. g. spot blotch (B. sorokiniana) oncereals and e. g. B. oryzae on rice and turfs; Blumeria (formerlyErysiphe) graminis (powdery mildew) on cereals (e. g. on wheat orbarley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: greymold) on fruits and berries (e. g. strawberries), vegetables (e. g.lettuce, carrots, celery and cabbages), rape, flowers, vines, forestryplants and wheat; Bremia lactucae (downy mildew) on lettuce;Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broad-leaved treesand evergreens, e. g. C. ulmi(Dutch elm disease) on elms; Cercosporaspp. (Cercospora leaf spots) on corn (e. g. Gray leaf spot: Czeae-maydis), rice, sugar beets (e. g. C. beticola), sugar cane,vegetables, coffee, soybeans (e. g. C. sojina or C. kikuchii) and rice;Cladosporium spp. on tomatoes (e. g. C. fulvum: leaf mold) and cereals,e. g. C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) oncereals; Cochliobolus (anamorph: Helminthosporium of Bipolaris) spp.(leaf spots) on corn (C. carbonum), cereals (e. g. C. sativus, anamorph:B. sorokiniana) and rice (e. g. C. miyabeanus, anamorph: H. oryzae);Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (e.g. C. gossypii), corn (e. g. C. graminicola: Anthracnose stalk rot),soft fruits, potatoes (e. g. C. coccodes: black dot), beans (e. g. C.lindemuthianum) and soybeans (e. g. C. truncatum or C. gloeosponbides);Corticium spp., e. g. C. sasakii (sheath blight) on rice; Coynesporacassiicola (leaf spots) on soybeans and ornamentals; Cycloconium spp.,e. g. C. oleaginum on olive trees; Cylindrocarpon spp. (e. g. fruit treecanker or young vine decline, teleomorph: Nectria or Neonectria spp.) onfruit trees, vines (e. g. C. liriodendri, teleomorph: Neonectrialiriodendri: Black Foot Disease) and ornamentals; Dematophora(teleomorph: Rosellinia) necatrix(root and stem rot) on soybeans;Diaporthespp., e. g. D. phaseolorum (damping off) on soybeans;Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. oncorn, cereals, such as barley (e. g. D. teres, net blotch) and wheat (e.g. D. tritici-repentis: tan spot), rice and turf; Esca (dieback,apoplexy) on vines, caused by Formitiporia (syn. Phellinus) punctata, F.mediterranea, Phaeomoniella chlamydospora (earlier Phaeoacremoniumch/amydosporum), Phaeoacremonium aleophilum and/or Bonyosphaeria obtusa;Elsinoe spp. on pome fruits (E. pyri), soft fruits (E. veneta:anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leafsmut) on rice; Epicoccumspp. (black mold) on wheat; Erysiphespp.(powdery mildew) on sugar beets (E. betae), vegetables (e. g. E. pis),such as cucurbits (e. g. E. cichoracearum), cabbages, rape (e. g. E.cruciferarum); Eutypa lata (Eutypa canker or dieback, anamorph:Cytosporina /ata, syn. Libertella b/epharis) on fruit trees, vines andornamental woods; Exserohilum (syn. Helminthosporium) spp. on corn (e.g. E. turcicum); Fusarium (teleomorph: Gibberella) spp. (wilt, root orstem rot) on various plants, such as F. graminearum or F cu/morum (rootrot, scab or head blight) on cereals (e. g. wheat or barley), Foxysporum on tomatoes, F. solani(f. sp. glycines now syn. F.virguliforme) and F. tucumaniae and F. brasiiiense each causing suddendeath syndrome on soybeans, and F. verticillioides on corn;Gaeumannomyces graminis (take-all) on cereals (e. g. wheat or barley)and corn; Gibberella spp. on cereals (e. g. G. zeae) and rice (e. g. G.fujikuroi: Bakanae disease); Glomerella cingulata on vines, pome fruitsand other plants and G gossypiion cotton; Grainstaining complex on rice;Guignardia bidwelli(black rot) on vines; Gymnosporangium spp onrosaceous plants and junipers, e. g. G. sabinae (rust) on pears;Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) oncorn, cereals and rice; Hemileia spp., e. g. H vastatrix (coffee leafrust) on coffee; Isariopsis clavispora (syn. Cladosporium vitis) onvines; Macrophomina phaseolina (syn. phaseoli) (root and stem rot) onsoybeans and cotton; Microdochium (syn. Fusarium) nivale (pink snowmold) on cereals (e. g. wheat or barley); Microsphaera diffusa (powderymildew) on soybeans; Monilinia spp., e. g. M.A. taxa, M.A. fructicolaand M.A. fructigena (bloom and twig blight, brown rot) on stone fruitsand other rosaceous plants; Mycosphaerella spp. on cereals, bananas,soft fruits and ground nuts, such as e. g. M.A. graminicola (anamorph:Septoria Septoria blotch) on wheat or M.A. qiensis (black Sigatokadisease) on bananas; Peronospora spp. (downy mildew) on cabbage (e. g. Pbrassicae), rape (e. g. P. parasitica), onions (e. g. P. destructor),tobacco (P. tabacina) and soybeans (e. g. P manshurica); Phakopsorapachyrhizi and P meibomiae (soybean rust) on soybeans; Phialophora spp.e. g. on vines (e. g. P. tracheiphila and P tetraspora) and soybeans (e.g. P. gregata: stem rot); Phoma lingam (root and stem rot) on rape andcabbage and P betae (root rot, leaf spot and damping-off) on sugarbeets; Phomopsisspp. on sunflowers, vines (e. g. P viticola: can andleaf spot) and soybeans (e. g. stem rot: P phaseoli, teleomorph:Diaporthe phaseolorum); Physoderma maydis (brown spots) on corn;Phytophthoraspp. (wilt, root, leaf, fruit and stem root) on variousplants, such as paprika and cucurbits (e. g. P. capsid, soybeans (e. g.P. megasperma, syn. P sojae), potatoes and tomatoes (e. g. P. infestanslate blight) and broad-leaved trees (e. g. P. ramorum: sudden oakdeath); Plasmodiophora brassicae (club root) on cabbage, rape, radishand other plants; Plasmopara spp., e. g. P. viticola (grapevine downymildew) on vines and P. halstedii on sunflowers; Podosphaeraspp.(powdery mildew) on rosaceous plants, hop, pome and soft fruits, e. g.P. leucotr/cha on apples; Polymyxa spp., e. g. on cereals, such asbarley and wheat (P. graminis) and sugar beets (P. betae) and therebytransmitted viral diseases; Pseudocercosporella herpotrichoides(eyespot, teleomorph: Tapesia yallundae) on cereals, e. g. wheat orbarley; Pseudoperonospora (downy mildew) on various plants, e. g. P.cubensis on cucurbits or P. humili on hop; Pseudopezicula tracheiphila(red fire disease or ,rotbrenner', anamorph: Phialophora) on vines;Puccinia spp. (rusts) on various plants, e. g. P triticina (brown orleaf rust), P. striiformis (stripe or yellow rust), P. hordei (dwarfrust), P graminis (stem or black rust) or P. recondita (brown or leafrust) on cereals, such as e. g. wheat, barley or rye, P. kuehnii (orangerust) on sugar cane and P. asparagi on asparagus; Pyrenophora (anamorph:Drechslera) tritici-repentis (tan spot) on wheat or P. teres (netblotch) on barley; Pyriculariaspp., e. g. P. oryzae (teleomorph:Magnaporthe grisea, rice blast) on rice and P. grisea on turf andcereals; Pythium spp. (damping-off) on turf, rice, corn, wheat, cotton,rape, sunflowers, soybeans, sugar beets, vegetables and various otherplants (e. g. P. ultimum or P. aphanidermatum); Ramularia spp., e. g. R.collo-cygni(Ramularia leaf spots, Physiological leaf spots) on barleyand R. beticola on sugar beets; Rhizoctonia spp. on cotton, rice,potatoes, turf, corn, rape, potatoes, sugar beets, vegetables andvarious other plants, e. g. R. solani (root and stem rot) on soybeans,R. solani (sheath blight) on rice or R. cerealis (Rhizoctonia springblight) on wheat or barley; Rhizopus stolonifer (black mold, soft rot)on strawberries, carrots, cabbage, vines and tomatoes; Rhynchosporiumsecalis (scald) on barley, rye and triticale; Sarocladium oryzae and S.attenuatum (sheath rot) on rice; Sclerotinia spp. (stem rot or whitemold) on vegetables and field crops, such as rape, sunflowers (e. g. S.sclerotiorum) and soybeans (e. g. S. rolfsiior S. sclerotiorum);Septoriaspp. on various plants, e. g. S. glycines (brown spot) onsoybeans, S. tritici (Septoria blotch) on wheat and S. (syn.Stagonospora) nodorum (Stagonospora blotch) on cereals; Uncinula (syn.Erysiphe) necator (powdery mildew, anamorph: Oidium tuckers) on vines;Setospaeria spp. (leaf blight) on corn (e. g. S. turcicum, syn.Helminthosporium turcicum) and turf; Sphacelotheca spp. (smut) on corn,(e. g. S. rediana: head smut), sorghum and sugar cane; Sphaerothecafuliginea (powdery mildew) on cucurbits; Spongospora subterranea(powdery scab) on potatoes and thereby transmitted viral diseases;Stagonospora spp. on cereals, e. g. S. nodorum (Stagonospora blotch,teleomorph: Leptosphaeria [syn. Phaeosphaeria] nodorum) on wheat;Synchytrium endobioticum on potatoes (potato wart disease); Taphrinaspp., e. g. T. deformans (leaf curl disease) on peaches and T. pruni(plum pocket) on plums; Thielaviopsis spp. (black root rot) on tobacco,pome fruits, vegetables, soybeans and cotton, e. g. T. basicola (syn.Chalara elegans); Tilletia spp. (common bunt or stinking smut) oncereals, such as e. g. T. tritici (syn. T. caries, wheat bunt) and T.controversa (dwarf bunt) on wheat; Typhula incarnata (grey snow mold) onbarley or wheat; Urocystis spp., e. g. U. occulta (stem smut) on rye;Uromyces spp. (rust) on vegetables, such as beans (e. g. U.appendiculatus, syn. U phaseoli) and sugar beets (e. g. U. betae);Ustilago spp. (loose smut) on cereals (e. g. U. nuda and U. avaenae),corn (e. g. U. maydis: corn smut) and sugar cane; Venturia spp. (scab)on apples (e. g. V. inaequalis) and pears; and Verticillium spp. (wilt)on various plants, such as fruits and ornamentals, vines, soft fruits,vegetables and field crops, e. g. V dahliae on strawberries, rape,potatoes and tomatoes.

The mixtures according to the present invention, respectively, are alsosuitable Afor controlling harmful fungi in the protection of storedproducts or harvest and in the protection of materials.

The term “protection of materials” is to be understood to denote theprotection of technical and non-living materials, such as adhesives,glues, wood, paper and paperboard, textiles, leather, paint dispersions,plastics, cooling lubricants, fiber or fabrics, against the infestationand destruction by harmful microorganisms, such as fungi and bacteria.As to the protection of wood and other materials, the particularattention is paid to the following harmful fungi: Ascomycetes such asOphiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophomaspp., Chaetomium spp., Humicola spp., Petriella spp., Trichurusspp.;Basidiomycetes such as Coniophoraspp., Coriolusspp., Gloeophyllum spp.,Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromycesspp., Deuteromycetes such as Aspergillus spp., Cladosporium spp.,Penicillium spp., Trichodermaspp., Alternaria spp., Paecilomyces spp.and Zygomycetes such as Mucor spp., and in addition in the protection ofstored products and harvest the following yeast fungi are worthy ofnote: Candida spp. and Saccharomyces cerevisae.

They are particularly important for controlling a multitude of fungi onvarious cultivated plants, such as bananas, cotton, vegetable species(for example cucumbers, beans and cucurbits), cereals such as wheat,rye, barley, rice, oats; grass coffee, potatoes, corn, fruit species,soya, tomatoes, grapevines, ornamental plants, sugar cane and also on alarge number of seeds. In a preferred embodiment, the inventive mixturesare used in soya (soybean), cereals and corn.

The inventive mixture can be applied to any and all developmental stagesof pests, such as egg, larva, pupa, and adult. The pests may becontrolled by contacting the target pest, its food supply, habitat,breeding ground or its locus with a pesticidally effective amount of theinventive mixtures or of compositions comprising the mixtures.

“Locus” means a plant, plant propagation material (preferably seed),soil, area, material or environment in which a pest is growing or maygrow.

In general, “pesticidally effective amount” means the amount of theinventive mixtures or of compositions comprising the mixtures needed toachieve an observable effect on growth, including the effects ofnecrosis, death, retardation, prevention, and removal, destruction, orotherwise diminishing the occurrence and activity of the targetorganisM.A. The pesticidally effective amount can vary for the variousmixtures/compositions used in the invention. A pesticidally effectiveamount of the mixtures/compositions will also vary according to theprevailing conditions such as desired pesticidal effect and duration,weather, target species, locus, mode of application, and the like.

As said above, the present invention comprises a method for improvingthe health of plants, wherein the plant, the locus where the plant isgrowing or is expected to grow or plant propagation material, from whichthe plant grows, is treated with an plant health effective amount of aninventive mixture.

The term “plant effective amount” denotes an amount of the inventivemixtures, which is sufficient for achieving plant health effects asdefined herein below. More exemplary information about amounts, ways ofapplication and suitable Aratios to be used is given below. Anyway, theskilled artisan is well aware of the fact that such an amount can varyin a broad range and is dependent on various factors, e.g. the treatedcultivated plant or material and the climatic conditions.

When preparing the mixtures, it is preferred to employ the pure activecompounds, to which further active compounds against pests, such asinsecticides, herbicides, fungicides or else herbicidal orgrowth-regulating active compounds or fertilizers can be added asfurther active components according to need.

The inventive mixtures are employed by treating the fungi or the plants,plant propagation materials (preferably seeds), materials or soil to beprotected from fungal attack with a pesticidally effective amount of theactive compounds. The application can be carried out both before andafter the infection of the materials, plants or plant propagationmaterials (preferably seeds) by the pests.

In the context of the present invention, the term plant refers to anentire plant, a part of the plant or the propagation material of theplant.

The inventive mixtures and compositions thereof are particularlyimportant in the control of a multitude of phytopathogenic fungi onvarious cultivated plants, such as cereals, e. g. wheat, rye, barley,triticale, oats or rice; beet, e. g. sugar beet or fodder beet; fruits,such as pomes, stone fruits or soft fruits, e. g. apples, pears, plums,peaches, almonds, cherries, strawberries, raspberries, blackberries orgooseberries; leguminous plants, such as lentils, peas, alfalfa orsoybeans; oil plants, such as rape, mustard, olives, sunflowers,coconut, cocoa beans, castor oil plants, oil palms, ground nuts orsoybeans; cucurbits, such as squashes, cucumber or melons; fiber plants,such as cotton, flax, hemp or jute; citrus fruit, such as oranges,lemons, grapefruits or mandarins; vegetables, such as spinach, lettuce,asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits orpaprika; lauraceous plants, such as avocados, cinnamon or camphor;energy and raw material plants, such as corn, soybean, rape, sugar caneor oil palm; corn; tobacco; nuts; coffee; tea; bananas; vines (TableAgrapes and grape juice grape vines); hop; turf; sweet leaf (also calledStevia); natural rubber plants or ornamental and forestry plants, suchas flowers, shrubs, broad-leaved trees or evergreens, e. g. conifers;and on the plant propagation material, such as seeds, and the cropmaterial of these plants.

Preferably, the inventive mixturs and compositions thereof, respectivelyare used for controlling a multitude of fungi on field crops, such aspotatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn,cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane;fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes,beans or squashes.

Preferably, treatment of plant propagation materials with the inventivemixtures and compositions thereof, respectively, is used for controllinga multitude of fungi on cereals, such as wheat, rye, barley and oats;potatoes, tomatoes, vines, rice, corn, cotton and soybeans.

The term “cultivated plants” is to be understood as including plantswhich have been modified by breeding, mutagenesis or genetic engineeringincluding but not limiting to agricultural biotech products on themarket or in development (cf. cera-gmc.org/, see GM crop databasetherein). Genetically modified plants are plants, which genetic materialhas been so modified by the use of recombinant DNA techniques that undernatural circumstances cannot readily be obtained by cross breeding,mutations or natural recombination. Typically, one or more genes havebeen integrated into the genetic material of a genetically modifiedplant in order to improve certain properties of the plant.

Such genetic modifications also include but are not limited to targetedpost-translational modification of protein(s), oligo- or polypeptides e.g. by glycosylation or polymer additions such as prenylated, acetylatedor farnesylated moieties or PEG moieties.

Plants that have been modified by breeding, mutagenesis or geneticengineering, e. g. have been rendered tolerant to applications ofspecific classes of herbicides, such as auxin herbicides such as dicambaor 2,4-D; bleacher herbicides such as hydroxylphenylpyruvate dioxygenase(HPPD) inhibitors or phytoene desaturase (PDS) inhibittors; acetolactatesynthase (ALS) inhibitors such as sulfonyl ureas or imidazolinones;enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitors, such asglyphosate; glutamine synthetase (GS) inhibitors such as glufosinate;protoporphyrinogen-IX oxidase inhibitors;

lipid biosynthesis inhibitors such as acetyl CoA carboxylase (ACCase)inhibitors; or oxynil (i. e. bromoxynil or ioxynil) herbicides as aresult of conventional methods of breeding or genetic engineering.Furthermore, plants have been made resistant to multiple classes ofherbicides through multiple genetic modifications, such as resistance toboth glyphosate and glufosinate or to both glyphosate and a herbicidefrom another class such as

ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors.These herbicide resistance technologies are e.g. described in PestManage M.A. Sci. 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005,269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Sci. 57, 2009,108; Austral. J. Agricult. Res. 58, 2007, 708; Science 316, 2007, 1185;and references quoted therein. Several cultivated plants have beenrendered tolerant to herbicides by conventional methods of breeding(mutagenesis), e. g. Clearfield® summer rape (Canola, BASF SE, Germany)being tolerant to imidazolinones, e. g. imazamox, or ExpressSun®sunflowers (DuPont, USA) being tolerant to sulfonyl ureas, e. g.tribenuron. Genetic engineering methods have been used to rendercultivated plants such as soybean, cotton, corn, beets and rape,tolerant to herbicides such as glyphosate and glufosinate, some of whichare commercially available under the trade names RoundupReady®(glyphosate-tolerant, Monsanto, U.S.A.), Cultivance® (imidazolinonetolerant, BASF SE, Germany) and LibertyLink® (glufosinate-tolerant,Bayer CropScience, Germany).

Furthermore, plants are also covered that are by the use of recombinantDNA techniques capable to synthesize one or more insecticidal proteins,especially those known from the bacterial genus Bacillus, particularlyfrom Bacillus thuringiensis, such as δ-endotoxins, e. g. CryIA(b),CryIA(c), CryIF, CryIF(a2), CryIIA(b), CryIIIIA, CryIIIIB(b1) or Cry9c;vegetative insecticidal proteins (VIP), e. g. VIP1, VIP2, VIP3 or VIP3A;insecticidal proteins of bacteria colonizing nematodes, e. g.Photorhabdus spp. or Xenorhabdus spp.; toxins produced by animals, suchas scorpion toxins, arachnid toxins, wasp toxins, or otherinsect-specific neurotoxins; toxins produced by fungi, suchStreptomycetes toxins, plant lectins, such as pea or barley lectins;agglutinins; proteinase inhibitors, such as trypsin inhibitors, serineprotease inhibitors, patatin, cystatin or papain inhibitors;ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin,luffin, saporin or bryodin; steroid metabolism enzymes, such as3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase,cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase; ionchannel blockers, such as blockers of sodium or calcium channels;juvenile hormone esterase; di-uretic hormone receptors (helicokininreceptors); stilben synthase, bibenzyl synthase, chitinases orglucanases. In the context of the present invention these insecticidalpro-teins or toxins are to be understood expressly also as pre-toxins,hybrid proteins, truncated or otherwise modified proteins. Hybridproteins are characterized by a new combination of protein domains,(see, e. g. WO 02/015701). Further examples of such toxins orgenetically modified plants capable of synthesizing such toxins aredisclosed, e. g., in

EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO03/18810 and WO 03/52073. The methods for producing such geneticallymodified plants are generally known to the person skilled in the art andare described, e. g. in the publications mentioned above. Theseinsecticidal proteins contained in the genetically modified plantsimpart to the plants producing these proteins tolerance to harmful pestsfrom all taxonomic groups of athropods, especially to beetles(Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) andto nematodes (Nematoda). Genetically modified plants capable tosynthesize one or more insecticidal proteins are, e. g., described inthe publications mentioned above, and some of which are commerciallyavailable such as YieldGard® (corn cultivars producing the Cry1Abtoxin), YieldGard® Plus (corn cultivars producing Cry1Ab and Cry3Bb1toxins), Starlink® (corn cultivars producing the Cry9c toxin), Herculex®RW (corn cultivars producing Cry34Ab1, Cry35Ab1 and the enzymePhosphinothricin-N-Acetyltransferase [PAT]); NuCOTN® 33B (cottoncultivars producing the Cry1Ac toxin), Bollgard® I (cotton cultivarsproducing the Cry1Ac toxin), Bollgard® II (cotton cultivars producingCry1Ac and Cry2Ab2 toxins); VIPCOT® (cotton cultivars producing aVIP-toxin); NewLeaf® (potato cultivars producing the Cry3A toxin);Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Bt11 (e. g.Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivarsproducing the CrylAb toxin and PAT enyzme), MIR604 from Syngenta SeedsSAS, France (corn cultivars producing a modified version of the Cry3Atoxin, c.f. WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium(corn cultivars producing the Cry3Bb1 toxin), IPC 531 from MonsantoEurope S.A., Belgium (cotton cultivars producing a modified version ofthe Cry1Ac toxin) and 1507 from Pioneer Overseas Corporation, Belgium(corn cultivars producing the Cry1F toxin and PAT enzyme).

Furthermore, plants are also covered that are by the use of recombinantDNA techniques capable to synthesize one or more proteins to increasethe resistance or tolerance of those plants to bacterial, viral orfungal pathogens. Examples of such proteins are the so-called“pathogenesis-related proteins” (PR proteins, see, e. g. EP-A 392 225),plant disease resistance genes (e. g. potato cultivars, which expressresistance genes acting against Phytophthora infestans derived from themexican wild potato Solanum bu/bocastanum) or T4-lysozym (e. g. potatocultivars capable of synthesizing these proteins with increasedresistance against bacteria such as Erwinia amylvora). The methods forproducing such genetically modified plants are generally known to theperson skilled in the art and are described, e. g. in the publicationsmentioned above.

Furthermore, plants are also covered that are by the use of recombinantDNA techniques capable to synthesize one or more proteins to increasethe productivity (e. g. bio mass production, grain yield, starchcontent, oil content or protein content), tolerance to drought, salinityor other growth-limiting environmental factors or tolerance to pests andfungal, bacterial or viral pathogens of those plants.

Furthermore, plants are also covered that contain by the use ofrecombinant DNA techniques a modified amount of substances of content ornew substances of content, specifically to improve human or animalnutrition, e. g. oil crops that produce healthpromoting long-chainomega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera®rape, DOW Agro Sciences, Canada).

Furthermore, plants are also covered that contain by the use ofrecombinant DNA techniques a modified amount of substances of content ornew substances of content, specifically to improve raw materialproduction, e. g. potatoes that produce increased amounts of amylopectin(e. g. Amflora® potato, BASF SE, Germany).

The separate or joint application of the compounds of the inventivemixtures is carried out by spraying or dusting the seeds, the seedlings,the plants or the soils before or after sowing of the plants or beforeor after emergence of the plants.

The inventive mixtures and the compositions comprising them can be usedfor protecting wooden materials such as trees, board fences, sleepers,etc. and buildings such as houses, outhouses, factories, but alsoconstruction materials, furniture, leathers, fibers, vinyl articles,electric wires and cables etc. from ants and/or termites, and forcontrolling ants and termites from doing harm to crops or human being(e.g. when the pests invade into houses and public facilities).

Customary application rates in the protection of materials are, forexample, from 0.01 g to 1000 g of active compound per m²treatedmaterial, desirably from 0.1 g to 50 g per m^(2.)

For use in spray compositions, the content of the mixture of the activeingredients is from 0.001 to 80 weights %, preferably from 0.01 to 50weight % and most preferably from 0.01 to 15 weight %.

1. A ternary fungicidal mixture comprising a)1-[2-[[1-4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one(I-3); b) fluxapyroxad as first compound 11; and c) a second compound IIselected from the group consisting of azoxystrobin; pyraclostrobin; andmetrafenon; wherein the ratio by weight of compound I-3, Hand secondcompound II in each combination of two ingredients in the mixture ofthree ingredients is from 1:100 to 100:1.
 2. A pesticidal compositioncomprising a liquid or solid carrier and the mixture of claim
 1. 3. Amethod for controlling phytopathogenic pests, wherein the pest, theirhabitat, breeding grounds, their locus or the plants to be protectedagainst pest attack, the soil or plant propagation material are treatedwith an effective amount of the mixture of claim
 1. 4. A method forimproving the health of plants, wherein the plant, the locus where theplant is growing or is expected to grow or plant propagation materialfrom which the plant grows are treated with an effective amount of themixture of claim
 1. 5. A method for protection of plant propagationmaterial from pests comprising contacting the plant propagationmaterials with the mixture of claim 1 in pesticidally effective amounts.6. The method of claim 5, wherein the mixture is applied in an amount offrom 0.01 g to 10 kg per 100 kg of plant propagation materials.
 7. Amethod for controlling phytopathogenic pests, wherein the pest, theirhabitat, breeding grounds, their locus or the plants to be protectedagainst pest attack, the soil or plant propagation material are treatedwith an effective amount of a ternary fungicidal mixture comprising, asacitve components a)1-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methyl-phenyl]-4-methyl-tetrazol-5-one(I-3); b) fluxapyroxad as first compound II; and c) a second compound IIselected from the group consisting of azoxystrobin; pyraclostrobin; andmetrafenon, wherein the ratio by weight of compound I-3, Hand secondcompound II in each combination of two ingredients in the mixture ofthree ingredients is from 1:100 to 100:1; wherein the active componentsare applied simultaneously, jointly or separately or in succession.
 8. Aplant propagation material treated with the mixture of claim 21 in anamount of from 0.01 g to 10 kg per 100 kg of plant propagationmaterials.